METHOD FOR HYDROGENATION OF ALPHA-METHYL-STYRENE Russian patent published in 2003 - IPC

Abstract RU 2211208 C2

FIELD: organic chemistry, chemical technology. SUBSTANCE: invention relates to method for hydrogenation of alpha-methylstyrene containing in alpha-methylstyrene fraction formed in processing cleavage products of cumene hydroperoxide. Hydrogenation is carried out at enhanced temperatures, preferably at 100-200 C and under pressure, preferably, at 10-30 atm and volume rate of liquid raw feeding 0.9-15 h-1. Alumopalladium catalyst containing palladium in the amount 0.2-0.3 wt.-% and treated additionally with copper nitrate solution with copper content 0.6-6.0 g/l followed by drying in air and thermal treatment in hydrogen atmosphere or hydrogen-containing gas. Invention provides reduced consumption of palladium and expanded range of temperature and pressure values. EFFECT: improved hydrogenation method. 2 cl, 2 tbl, 11 ex

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RU 2 211 208 C2

Authors

Kharlampidi Kh.Eh.

Karalin Eh.A.

Ksenofontov D.V.

Izmajlov R.I.

Miroshkin N.P.

Fafanov G.P.

Kudrjashov V.N.

Cherevin V.F.

Maslov A.I.

Kalashnikov Ju.S.

Dates

2003-08-27Published

2001-10-08Filed