FIELD: nitrogen compounds production.
SUBSTANCE: invention relates to catalyst and ammonia conversion process used in weak nitric acid production. Ammonia conversion catalyst represents a honeycomb-structure block catalyst based on mixed oxides depicted by general formula: ((2-x)MgO·xMeO)·2-y)Al2O5·Al2O3·(5+y(2-x))SiO2, where x=0-2, y=0-0.5, and Me is Mn, Fe, Co, Ni, Cu, Cr, V, or their mixtures, forming frame structure of cordierite with thermal expansion factor ·10-7- 10-5 K-1 within temperature range up to 900оС. Catalytic conversion of ammonia involves passing gaseous reaction mixture comprising ammonia and oxygen-containing gas through double-step catalytic system formed by a variety of ways including combination with trapping platinoid gauzes and/or inert charge in the first step and claimed catalyst in the second step.
EFFECT: increased activity and selectivity of catalyst as well as its resistance to thermocycles.
4 cl, 2 tbl, 10 ex
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Authors
Dates
2004-08-27—Published
2003-10-13—Filed