FIELD: chemistry.
SUBSTANCE: invention relates to catalysts for the oxidation of ammonia in a block honeycomb structure comprising iron, aluminium, silicon oxides and stabilising additives, with the following ratio of components: iron oxide - 65-80; aluminium oxide - 19-30; silicon oxide 0.01-5, stabilising additive - 1-16. Moreover, as a stabilizing additive, the catalyst contains mixed oxides with the cordierite structure of the general formula: [(2-x)MgO⋅xMe1O]⋅[(2-y)Al2O3⋅yMe22O3][(5-z)SiO2 zMe3O2], where x=0-2; Me1=Ca, Na, K, Mn, Fe or mixtures thereof; y=0-0.5; Me2=Mn, Fe; z=0-0.5; Me3=Ti.
EFFECT: high strength and thermal stability, achieved due to additives introduced into the block catalyst of honeycomb structure from affordable and cheap raw materials.
1 dwg, 1 tbl, 11 ex
Title | Year | Author | Number |
---|---|---|---|
CATALYST AND METHOD OF CONVERTING AMMONIA | 2008 |
|
RU2368417C1 |
CATALYST AND AMMONIA CONVERSION PROCESS | 2003 |
|
RU2234977C1 |
CATALYST, ITS PREPARATION METHOD, AND PROCESS OF AMMONIA OXIDATION | 2020 |
|
RU2748990C1 |
CATALYTIC ELEMENT FOR HETEROGENEOUS HIGH-TEMPERATURE REACTIONS | 2018 |
|
RU2693454C1 |
CATALYST, PREPARATION METHOD THEREOF AND AMMONIA OXIDATION METHOD | 2010 |
|
RU2430782C1 |
METHOD OF PREPARING CATALYST AT OXIDIZING AMMONIA | 1990 |
|
SU1676142A1 |
CATALYST, PREPARATION METHOD THEREOF AND METHOD OF DECOMPOSING NITROGEN OXIDE | 2010 |
|
RU2430781C1 |
CATALYST FOR AMMONIA OXIDATION | 1997 |
|
RU2117528C1 |
METHOD FOR THERMAL TREATMENT OF IRON OXIDE-BASED BLOCK CATALYST WITH CELLULAR STRUCTURE | 2009 |
|
RU2429071C1 |
HONEYCOMB-STRUCTURE BLOCK CATALYST FOR SELECTIVE OXIDATION OF AMMONIA INTO NITROGEN OXIDE | 2002 |
|
RU2207904C1 |
Authors
Dates
2017-07-03—Published
2016-06-08—Filed