FIELD: inorganic synthesis.
SUBSTANCE: invention provides heterometallic neodymium (III) and iron (III) malate having formula I:
appropriate for synthesis of mixed oxides with perovskite structure, which are used as catalysts in oxidative catalysis of unsaturated acyclic hydrocarbons and as materials used in microwave frequency technology and in computer memory materials. Preparation consists in electrolysis of concentrated aqueous solution of neodymium (III) chloride and malic acid at 1:3 ratio in presence of pyridine with pressed reduced iron anode and inert cathode at anode current density 1 A/cm2, followed by separating precipitate and washing it with organic solvent before drying.
EFFECT: enlarged assortment of oxidation catalysts.
2 cl, 1 dwg, 2 tbl
Title | Year | Author | Number |
---|---|---|---|
METHOD OF PRODUCING HETEROMETAL Fe (III) AND Nd (III) MALATE | 2007 |
|
RU2351602C1 |
PROCESS FOR PREPARING TETRAKIS-μ-(METHOXO)-(METHOXO) PENTAKIS(ACETYLACENATO) COPPER (II), REE (III) OF BARIUM | 1991 |
|
RU2063400C1 |
EXHAUST GAS TREATMENT CATALYST, METHOD OF PREPARATION THEREOF, AND A DEVICE BASED ON EXHAUST GAS TREATMENT CATALYST | 2004 |
|
RU2315657C1 |
COPPER (II) IMIDAZOLEMALATE, DEMONSTRATING ANTIBACTERIAL ACTIVITY, AND METHOD OF OBTAINING THEREOF | 2015 |
|
RU2574400C1 |
METHOD OF ELECTRIC OXIDATION OF CERIUM IONS (III) | 2018 |
|
RU2673809C1 |
METHOD OF PRODUCING INDATES OF RARE-EARTH ELEMENTS InO | 2018 |
|
RU2688606C1 |
OPTIMISATION METHOD OF CONDUCTIVITY, WHICH IS PROVIDED BY DISPLACEMENT OF H+ PROTONS AND/OR OH- IONS IN CONDUCTING MEMBRANE | 2008 |
|
RU2497240C2 |
METHOD OF PRODUCTION OF METALLIC MAGNESIUM (VERSIONS) AND METHOD OF PRODUCTION OF METALLIC MAGNESIUM FROM ALLOY OF MAGNESIUM AND RARE-EARTH METAL | 1995 |
|
RU2107753C1 |
PROCESS OF PRODUCTION OF ARSENIC ACID BY ELECTROCHEMICAL OXIDATION OF AQUEOUS SUSPENSION OF ARSENIC OXIDE (III) | 2000 |
|
RU2202002C2 |
METHOD OF PREPARING OF ALKOXY-DERIVATIVES OF IRON (III) | 1991 |
|
RU2017712C1 |
Authors
Dates
2005-06-27—Published
2003-05-15—Filed