FIELD: organic chemistry.
SUBSTANCE: tert-butyl is produced by isobutylene hydrochlorination at temperature from -18°C to -20°C in isobutylene/hydrogen chloride volume ratio of 1.0-1.1:1.0. Reaction mixture is subsequently passed through column filled with ion exchange resin preferably based on polyethylene polyamines and epichlorohydrin, at 1-50°C and at rate of 1.4-1.8 l/h.
EFFECT: method for tert-butyl production of increased yield and improved quality.
1 dwg, 9 ex, 1 tbl
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Authors
Dates
2006-02-20—Published
2004-12-22—Filed