FIELD: inorganic chemistry, chemical technology.
SUBSTANCE: invention relates to manufacturing elemental sulfur from sulfur oxide gas, for example, from nonferrous metallurgy gases comprising sulfur dioxide. Method involves reduction of sulfur oxide gas comprising sulfur dioxide with hydrocarbons at increased temperature and the following processing in the presence of a catalyst to form elemental sulfur by Claus method. Before the first catalytical step in Claus-processing method reduced sulfur oxide gas is passed through additional step at temperature 350-600°C followed by its cooling to temperature 230-250°C and then subjected for catalytic Claus-processing procedure. Method allows decreasing the specific consumption of reducing agent, for example, natural gas (methane) and to enhance the yield of the end product. Invention can be used in plants of chemical, petroleum chemical, gas-processing and metallurgy industries.
EFFECT: improved preparing method.
1 dwg, 1 ex
Title | Year | Author | Number |
---|---|---|---|
COKE GAS DESULFURIZATION PROCESS | 2001 |
|
RU2210536C1 |
METHOD FOR PRODUCTION OF ELEMENTARY SULFUR FROM EMISSION GASES CONTAINING SULFUR DIOXIDE | 2002 |
|
RU2221742C2 |
METHOD OF OBTAINING ELEMENTARY SULPHUR FROM OXYGEN-CONTAINING METALLURGICAL SULPHUR DIOXIDE GAS | 2007 |
|
RU2356832C2 |
CATALYTIC COMPOSITION BASED ON TITANIUM AND ALUMINUM OXIDE COMPOUNDS AND ITS APPLICATION | 2021 |
|
RU2775472C1 |
METHOD OF PRODUCING ELEMENTARY SULPHUR FROM SULPHUR DIOXIDE-CONTAINING EXHAUST GAS | 2011 |
|
RU2474533C1 |
METHOD OF OBTAINING ELEMENTAL SULPHUR FROM SULPHUR DIOXIDE-CONTAINING DISCHARGE GAS | 2013 |
|
RU2523204C1 |
METHOD OF NEUTRALIZING SULPHUR COMPOUNDS OF ACID GASES AFTER AMINE PURIFICATION OF LOW-SULPHUR HYDROCARBON GAS | 2023 |
|
RU2824992C1 |
METHOD OF PREPARING CALCIUM SULFIDIZER TO PRECIPITATE HEAVY NONFERROUS METALS FROM ACIDIC SULFATE SOLUTIONS AND LIQUID PHASE OF FERRIFEROUS HYDRATE SLURRIES | 1997 |
|
RU2120484C1 |
CATALYST COMPOSITION SUITABLE FOR CATALYTIC REDUCTION OF SULPHUR COMPOUND CONTAINED IN GAS STREAM, AND METHOD OF PRODUCING AND USING SAID COMPOSITION | 2008 |
|
RU2461424C2 |
METHOD OF SULFUR PRODUCING | 1991 |
|
RU2022916C1 |
Authors
Dates
2006-04-27—Published
2004-05-11—Filed