FIELD: organic chemistry, chemical technology.
SUBSTANCE: invention proposes a method for preparing propylene oxide wherein (I) propene is subjected for conversion with hydrogen peroxide in the presence of methanol to propylene oxide to obtain a mixture (CI) containing propylene oxide, methanol, water and unreacted hydrogen peroxide; (II) from mixture (CI) mixture (CII) is removed that contains methanol, water and hydrogen peroxide to obtain mixture (Ca) containing propylene oxide; and (III) from mixture CII water is removed to obtain mixture (CIII) containing methanol and methyl formate. Invention provides enhancing yield of the end product and decreasing formation of by-side products.
EFFECT: improved preparing method.
9 cl, 1 ex
Title | Year | Author | Number |
---|---|---|---|
PROPYLENE OXIDE PRODUCTION PROCESS | 2001 |
|
RU2276668C2 |
PROPYLENE EPOXIDATION PROCESS | 2002 |
|
RU2314300C2 |
METHOD OF OBTAINING ALKENOXIDE | 2004 |
|
RU2339628C2 |
PROPENE EPOXIDATION METHOD | 2006 |
|
RU2388755C2 |
PROPYLENE OXIDE RECOVERY FROM PROPYLENE OXIDE AND METHANOL MIXTURE | 2005 |
|
RU2357963C2 |
ISOLATION OF PROPYLENOXIDE FROM MIXTURE, CONTAINING PROPYLENOXIDE AND METHANOL | 2005 |
|
RU2341519C2 |
METHOD OF PRODUCING OLEFIN OXIDE | 2008 |
|
RU2480459C2 |
OLEFIN EPOXIDATION METHOD WITH IMPROVED ENERGY BALANCE | 2006 |
|
RU2371439C2 |
METHOD OF PROPYLENE OXIDE PREPARATION | 2004 |
|
RU2324689C2 |
METHOD OF PRODUCING PROPYLENE OXIDE | 2010 |
|
RU2529859C2 |
Authors
Dates
2006-05-27—Published
2001-07-05—Filed