FIELD: chemistry.
SUBSTANCE: method of producing 2-phenyl-3-alkylquinolines of formula (1) 
, where R = H, CH3, C2H5, includes reacting benzylamine with an aniline and aliphatic alcohols RCH2CH2OH (where R assumes values given above) and CCl4 in the presence of an iron-containing catalyst (FeCl3, FeCl3·6H2O, FeCl2·4H2O, Fe(C5H5)2, Fe(acac)3, Fe(OAc)2 and Fe2(CO)9) in the molar ratio: [Fe]:[benzylamine ]:[aniline]:[alcohol]:[CCl4]=[0.5-1]:[100]:[10-100]:[200-400]:[100-200] at 130-150°C for 4-8 hours.
EFFECT: method of producing 2-phenyl-3-alkylquinolines, characterised by high output and low cost of the end product owing to use of affordable initial reagents.
1 tbl, 3 ex
| Title | Year | Author | Number |
|---|---|---|---|
| METHOD FOR SUBSTITUTED QUINOLINES PRODUCTION FROM ANILINE, 1,2-DIOLS AND CCL4 UNDER IRON CATALYSTS | 2015 |
|
RU2614251C2 |
| METHOD FOR THE PREPARATION OF BENZIMIDAZOLES | 2022 |
|
RU2789332C1 |
| METHOD OF OBTAINING SUBSTITUTED QUINOLINES FROM ANILINE, 1,3-DIOLS AND CCl4 UNDER ACTION OF IRON-CONTAINING CATALYSTS | 2013 |
|
RU2561503C2 |
| 1-DICHLOROMETHYLISOQUINOLINE SYNTHESIS METHOD | 2008 |
|
RU2402535C2 |
| 1-ACETYLISOQUINOLINE SYNTHESIS METHOD | 2009 |
|
RU2404166C1 |
| METHOD OF OBTAINING METHYL ESTER OF 2-BENZO[b]FURANCARBOXYLIC ACID | 2010 |
|
RU2467004C2 |
| METHOD FOR PRODUCING ALKYL ETHERS OF METOXYBENZOIC ACIDS | 2016 |
|
RU2640206C1 |
| METHOD FOR OBTAINING ALKYL ESTERS OF HYDROXYBENZOIC ACIDS | 2017 |
|
RU2675496C1 |
| METHOD OF PRODUCING 1-CHLOROADAMANTANE | 2011 |
|
RU2486169C2 |
| 5-ACETYLPYRROLE-2-CARBOXYLIC ACID METHYL ETHER SYNTHESIS METHOD | 2008 |
|
RU2404162C2 |
