FIELD: organic chemistry.
SUBSTANCE: Claimed method includes reaction of fullerene[60] (C60) with triethylaluminum (AlEt3) in C60:AlEt3 molar ratio of 1:(25-35) in presence of Cp2ZrCl2 as catalyst in amount of 15-25 mol.% based on C60 in argon atmosphere, in toluene medium under atmospheric pressure and at room temperature for 8 hours followed by addition to reaction mass at -15°C copper chloride (CuCl) catalyst in amount of 15-20 mol % based on C60 and methylvinyldichlorosilane in equimolar amount in relation to AlEt3. Further reaction mass is agitated at room temperature for 6-10 hours followed by hydrolysis of reaction mass.
EFFECT: method of increased yield.
1 tbl, 7 ex
| Title | Year | Author | Number |
|---|---|---|---|
| METHOD FOR PRODUCTION OF 1-HYDROXY-2,3-[60]FULLEROCYCLOPENTANECARBOXYLIC ACID ETHYL ESTER | 2005 |
|
RU2283830C1 |
| METHOD OF PREPARING 1-[3-HYDROXY-3-ARYLPROP-1-YL]-1,2-DIHYDRO[60]FULLERENES | 2005 |
|
RU2290367C1 |
| METHOD FOR PREPARING 1-[3-HYDROXY-3-(PYRID-4-YLPROP-1-YL]-1,2-DIHYDRO[60]FULLERENES | 2005 |
|
RU2294929C2 |
| METHOD FOR PREPARING 1-ETHYL-3,3-DIALKYL-6,7-FULLERENO[60]CYCLOHEPTA-2-OX-1-ALANES | 2002 |
|
RU2206570C1 |
| METHOD FOR PREPARING 2,3-FULLERENO[60]CYCLOPENTANOLS | 2003 |
|
RU2238262C1 |
| METHOD FOR PREPARING 1-[3-HYDROXY-4-(FUR-2-YL)PROP-1-YL]-1,2-DIHYDRO[60]FULLERENES | 2005 |
|
RU2290401C1 |
| METHOD FOR PREPARING 1-[1-HYDROXY-1-(PYRID-4-YL)METHYL]-1,2-DIHYDRO[60]FULLERENES | 2005 |
|
RU2294928C2 |
| METHOD FOR PREPARING 1-[3'-HYDROXY-3'-ALKYL-(3',3'-DIALKYL)]-N-PROPYL-2-HYDRO[60]FULLERENES | 2003 |
|
RU2238929C1 |
| METHOD FOR PREPARING 1-(3',3'-DIALKOXYPROP-1'-YL)-2-HYDRO[60]FULLERENES | 2003 |
|
RU2238930C1 |
| METHOD OF SYNTHESIS OF 1-ETHYL-2,3-FULLERENEALUMINOCYCLO- -PENTANES | 1997 |
|
RU2132332C1 |
