FIELD: organic chemistry, chemical technology.
SUBSTANCE: invention relates to a method for synthesis of vinyl chloride by the liquid-phase dehydrochlorination process of 1,2-dichloroethane. As reagent for the liquid-phase dehydrochlorination process of 1,2-dichloroethane the method involves using alcoholic solutions of quaternary ammonium salts of the general formula: [R1-R2-R3-R4N]+OR- wherein R1-R2-R3 mean (C1-C4)-alkyl; R3-R4 mean propenyl, β- or γ-chloropropenyl; R means (C1-C4)-alkyl, benzyl synthesized by electrolysis of corresponding quaternary ammonium salts in electrolyzers with ion-exchange membranes. Invention provides the development of wasteless, highly efficient, ecologically pure technology of synthesis of vinyl chloride and simplifying a method for synthesis of vinyl chloride based on decreasing temperature and pressure in carrying out the process.
EFFECT: improved method of synthesis.
2 cl, 1 tbl, 1 dwg, 4 ex
Title | Year | Author | Number |
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0 |
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SU500750A3 | |
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Authors
Dates
2007-01-27—Published
2005-10-05—Filed