METHOD OF PRODUCTION OF KETONES AND CATALYST FOR REALIZATION OF THIS METHOD Russian patent published in 2007 - IPC C07C49/04 C07C49/08 C07C49/10 C07C45/27 B01J31/18 B01J23/16 

FIELD: main organic synthesis.

SUBSTANCE: proposed method is used for production of ketones, for example dimethyl ketone (CH₃COCH₃), methyl ethyl ketone (CH₃COC₂H₅) by direct catalytic oxidation of respective alkenes, for example propylene, n-butenes, as well as catalysts for realization of this method. Oxidation of alkenes is performed in the presence of metallocomplex catalysts containing organic component where nitrogen oxide (I) is used as oxidant. Used for process is catalyst on base of peroxopolyoxo metallate complexes of terakis (oxo diperoxo metallate)-phosphate (3-) together with quaternary ammonium cationes having formula Q₃{PO₄[MeO(O₂)₂]₄}, where Me-Mo, W,V; Q₃ is quaternary ammonium catione containing alkyl chains C₄-C₈ or N-hexadecyl pyridinium.

EFFECT: enhanced selectivity of process.

10 cl, 14 ex