PENTA-{[POLY-(ETHYLENEOXY)CARBONYLMETHYL]-HETERYLONIUM}-DERIVATIVES OF TRIPHENOLS AND METHOD FOR THEIR PREPARING, METHOD FOR HYDROPHILIZATION OF EPOXY POLYMERS, METALLIC ARTICLE FETTLED BY THIS POLYMER AND METHOD FOR PREVENTION OF PRECIPITATION OF ASPHALT-RESINOUS-PARAFFIN DEPOSITS FROM PETROLEUM Russian patent published in 2008 - IPC C07C217/50 C07C213/00 C09K8/524 F16L9/02 E21B37/06 

Abstract RU 2318800 C1

FIELD: organic chemistry, chemical technology, polymers.

SUBSTANCE: invention relates to a method for synthesis of novel compounds - penta-{[poly-(ethyleneoxy)carbonylmethyl]heterylonium}-derivatives of triphenols of the formula: . Method for synthesis of the claimed compounds involves interaction of monochloroacetic acid with an oxyethylated product of condensation of alkyl-(C8-C10)-phenol with 4,4-dimethyldioxane-1,3 in the presence of acid catalyst in medium of a boiling organic solvent and azeotropic removing formed water and the following treatment of the synthesized reaction product with heterocyclic amino-compounds at heating in the molar ratio - oxyethylated product : monochloroacetic acid : heterocyclic amino-compound = 1:(5.0-5.5):(5.0-5.5), respectively. Synthesized compounds possess properties of hydrophilizing modifying agents of polymers. Invention proposes a simple method for hydrophilization of epoxy polymers in their synthesis by mixing epoxy resin, a hardening agent and a modifying agent chosen from the claimed compounds in the amount 0.7-1.5 weight%. Fettling metallic articles (pipelines) by these covers increases their exploitation period from 6 months to 23-24 months based on decreasing precipitation of asphalt-resinous-paraffin deposits from petroleum.

EFFECT: improved method of synthesis, improved and valuable properties of polymers.

9 cl, 1 tbl, 11 ex

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RU 2 318 800 C1

Authors

Fakhretdinov Pavel Sagitovich

Romanov Gennadij Vasil'Evich

Margulis Boris Jakovlevich

Dobroskok Boris Evlampievich

Tuzova Valentina Borisovna

Jakimova Natal'Ja Viktorovna

Dates

2008-03-10Published

2006-07-19Filed