FIELD: petrochemical process catalysts.
SUBSTANCE: invention relates to a process and apparatus for thermal removal of coke from loose mass of granulated selective zeolite catalyst based on pentasil-type crystalline aluminosilicates for production of olefins having 2 and 3 carbon atoms from mixture of olefins having 4-8 carbon atoms or methanol or dimethyl ether. Process is carried out in reactor (1) wherein catalyst is used in the form of loose mass. In preliminary stage, reactor (1) is flushed by heated nitrogen stream at entry temperature 460-500°C in order to replace hydrocarbons out of catalyst. Then, reactor is cooled by heated nitrogen stream at entry temperature from 420 to less than 460°C. In the main stage, nitrogen/air mix slowly heated to entry temperature 460-500°C is passed through reactor and, in additional stage, reactor is flushed by nitrogen stream heated to entry temperature 460-500°C in order to wash out air out of zeolite catalyst. Apparatus for implementation of described process comprises heater (6) designed to heat nitrogen and nitrogen/air streams, in series connected reactor (1), in series connected air cooler (12), and in series connected pressure gun (14).
EFFECT: preserved catalytically activity of zeolite catalyst.
10 cl, 1 dwg
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Authors
Dates
2008-03-20—Published
2002-11-29—Filed