FIELD: chemistry.
SUBSTANCE: principle refers to the method of producing olefin oxide, method of application of the produced olefin oxide and the production of 1,2-diol or simple ether 1-,2-diol and catalytic composition. The mentioned catalytic composition for the production of olefin oxide contains silver and activating agent, that consists of an alkaline metal on a bearer where the activating alkaline metal contains potassium whose quantity is not less than 5 mcmol/g of metal relative to the mass of the catalytic composition and not less than 1 mcmol/g alkaline metal from the group that contains lithium, sodium and there mixtures in which the mentioned bearer contains calcium carbonate joined with silver. The relative mass of silver: calcium carbonate is 1:5 to 1:100, and the unit surface area of the bearer is from 1 m/g to 20 m/g, and the apparent porosity of the bearer is 0.05 ml/g to 2 ml/g. The explained method of producing olefin oxide, include interaction of olefin, that has 3 or more carbon atoms, with oxygen in the presence of the above mentioned catalytic system, and the method of producing 1,2-diol or simple ether 1,2-diol, in which the olefin oxide is produced from the explained method.
EFFECT: increasing of selectivity, activity and stability of catalyst.
10 cl, 5 tbl, 37 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD OF PRODUCING OLEFIN OXIDE, METHOD OF USING OLEFIN OXIDE AND CATALYTIC COMPOSITION | 2003 |
|
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METHOD OF PRODUCING OLEFIN OXIDE | 2008 |
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RU2660419C2 |
METHOD OF SYNTHESIS OF OLEFIN OXIDES BY DIRECT OXIDATION OF OLEFINS, CATALYTIC COMPOSITION FOR THIS PROCESS AND METHOD OF ITS REGENERATION | 1997 |
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METHOD FOR OBTAINING ETHYLENEOXIDE WITH IMPROVED REGULATION | 2011 |
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RU2581365C2 |
METHOD AND SYSTEMS FOR EPOXIDATION OF OLEFIN | 2002 |
|
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|
RU2129465C1 |
Authors
Dates
2008-06-10—Published
2003-10-27—Filed