FIELD: chemistry.
SUBSTANCE: invention pertains to the method of oxidation of hydrocarbons using oxygen in trifluoroacetic acid and can be used particularly for oxidation of alkanes, cycloalkanes, alkylaromatic hydrocarbons, alkenes, cycloalkenes. The method involves saturation of trifluoroacetic acid with oxygen, after which, the initial hydrocarbon is added to the obtained reaction medium and is kept until depletion of bound oxygen with obtaining the corresponding oxygen containing compound.
EFFECT: invention allows carrying out a process of selective partial catalytic oxidation of hydrocarbons with obtaining different oxygen containing organic compounds without use of high temperature and traditional catalyst systems based on transition metals.
1 tbl, 5 ex
| Title | Year | Author | Number |
|---|---|---|---|
| METHOD FOR OXIDATION OF HYDROCARBONS | 1998 |
|
RU2210562C2 |
| METHOD OF OBTAINING ALKYLAROMATIC MONOCARBOXYLIC ACIDS | 2007 |
|
RU2348608C1 |
| METHOD FOR OXIDATION OF HYDROCARBON, ALCOHOL AND/OR KETONE | 2001 |
|
RU2235714C1 |
| METHOD OF ISOLATION AND PURIFICATION OF DICARBOXYLIC ACID FORMED UPON DIRECT OXIDATION OF CYCLIC C3-C20 HYDROCARBON | 1999 |
|
RU2208604C2 |
| METHOD FOR OXIDATION OF HYDROCARBON TO ACID | 2002 |
|
RU2274633C2 |
| CATALYTIC ALKANE OXIDATION PROCESS | 2002 |
|
RU2284986C2 |
| METHOD OF OXIDIZING HYDROCARBONS INTO ACIDS | 2001 |
|
RU2248345C2 |
| CATALYST AND METHOD FOR OBTAINING HIGHER 2-KETONES C5-C10 | 2022 |
|
RU2790246C1 |
| METHOD FOR PRODUCTION OF DICARBOXYLIC ACIDS | 2003 |
|
RU2297997C2 |
| CARBOXYLIC ACID SYNTHESIS METHOD | 2006 |
|
RU2398757C2 |
