COMPOSITION OF EPOXYBISMALEIMIDE BINDING AGENT FOR PREPREGS (VERSIONS), METHOD OF OBTAINING EPOXYBISMALEIMIDE BINDING AGENT (VERSIONS), PREPREG AND ARTICLE Russian patent published in 2008 - IPC C08L63/00 C09J163/00 C08J5/24 B32B27/38 C08G59/40 

Abstract RU 2335514 C1

FIELD: chemistry.

SUBSTANCE: first version of invention claims composition of the following component ratio, wt %: N,N,N',N'-tetraglycidyl-4,4'-diamino-3,3'-dichlordiphenylmethane 24.8÷42.1 and triglycidyl-aminophenol as polyfunctional epoxy resins 11.5÷25.8, polycrystalline powder of N,N'-hexamethylenebismaleimide as bismaleimide 25.8÷41.3, polycrystalline powder of 4,4'-diaminodiphenylsulfone as solidifier 17.4÷22.6. Second version of invention claims composition of the following component ratio, wt %: N,N,N',N'-tetraglycidyl-4,4'-diamino-3,3'-dichlordiphenylmethane 21.6÷49.5 and triglycidyl bisphenol-A ether as polyfunctional epoxy resins 16.1÷32.4, polycrystalline powder of N,N'-hexamethylenebismaleimide as bismaleimide 3.5÷27.0, polycrystalline powder of 4,4'-diaminodiphenylsulfone as solidifier 19.0÷25.8. Method of obtaining the claimed compositions involves addition of polycrystalline 4,4'-diaminodiphenylsulfone powder to homogenous polyfunctional epoxy resin melt during stirring at 120÷130°C in minimum time sufficient for its complete dissolution. Then the temperature of obtained homogenous melt is lowered to 90÷100°C. By further stirring polycrystalline powder of N,N'-hexamethylenebismaleimide is added to the melt in minimum time sufficient for its complete dissolution. Prepreg includes components at the following ratio, wt %: the claimed epoxybismaleimide binding agent 20-48 and fiber filler 52-80. An article is produced by the claimed prepreg modelling.

EFFECT: improved durability of binding agent and increased vitrifying temperature and flexural strength of article.

6 cl, 2 tbl, 10 ex

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Authors

Dolmatov Stanislav Aleksandrovich

Tomchani Ol'Ga Vasil'Evna

Vorvul' Svetlana Vladimirovna

Kotukhova Alla Mikhajlovna

Khabenko Aleksej Vasil'Evich

Shul' Galina Sergeevna

Mukhin Nikolaj Vasil'Evich

Vymorkov Nikolaj Vladimirovich

Petrokovskij Sergej Aleksandrovich

Bakhtin Aleksandr Georgievich

Dates

2008-10-10Published

2006-12-27Filed