FIELD: chemistry.
SUBSTANCE: claimed invention relates to field of organic chemistry, namely to method of obtaining 2-alkyl-5-phenyl-3,4- fullero[60]tetrahydrothiophenes of formula (I) 
. Essence of method lies in interaction of fullerene C60 with alkylbenzylsulfides in presence of catalyst Cp2ZrCl2 in toluol medium at temperature 140-160°C during 4-8 hours. Target product output is 42-70%.
EFFECT: obtaining compounds, which can be used as complex-forming agents, sorbents, biologically active compounds, as well as in creation of novel materials with set electronic, magnetic and optical properties.
1 tbl, 11 ex
| Title | Year | Author | Number |
|---|---|---|---|
| METHOD OF OBTAINING 2,5-DIALKYL-3,4-FULLERO[60]TETRAHYDROTHIOPHEN-1-ONS | 2007 |
|
RU2342377C2 |
| METHOD OF OBTAINING 3,4-FULLERO[60]TETRAHYDROTHIOPHEN-1-ON | 2007 |
|
RU2342381C2 |
| METHOD OF OBTAINING 2,5-DIALKYL-3,4- FULLERO[60]TETRAHYDROTHIOPHENES | 2007 |
|
RU2342382C2 |
| METHOD OF OBTAINING 3,4-FULLERO [60]TETRAHYDROTHIOPHENE | 2007 |
|
RU2342378C2 |
| METHOD OF OBTAINING 2,5-DIPHENYL-3,4- FULLERO[60]TETRAHYDROTHIOPHEN | 2007 |
|
RU2342379C2 |
| METHOD OF OBTAINING 2,5-DIPHENYL-3,4-FULLERO[60]TETRAHYDROTHIOPHEN-1-ON | 2007 |
|
RU2342380C2 |
| METHOD OF PRODUCING 2,3-FULLERO-7-THIABICYCLO [2,2,1]HEPTANE | 2007 |
|
RU2349593C1 |
| METHOD OF PRODUCING 1-ALKOXY- OR 1-CYCLOALKOXY-1,2-DIHYDRO[60]FULLERENE | 2008 |
|
RU2384561C2 |
| METHOD FOR PREPARING 1-[3'-HYDROXY-3'-ALKYL-(3',3'-DIALKYL)]-N-PROPYL-2-HYDRO[60]FULLERENES | 2003 |
|
RU2238929C1 |
| METHOD OF OBTAINING POLYHYDRO[60]FULLERENES | 2007 |
|
RU2348601C1 |
