FIELD: chemistry.
SUBSTANCE: claimed invention relates to field of organic chemistry, namely to method of obtaining 2,5-dialkyl-3,4-fullero[60]tetrahydrothiophenes of formula (I) . Essence of method lies in interaction of fullerene C60 with dialkylsulfide in presence of catalyst Cp2TiCl2 in toluol medium at temperature 140-160°C during 5-7 hours. Target product output is 47-70%.
EFFECT: obtaining compounds, which can be used as complex-forming agents, sorbents, biologically active compounds, as well as in creation of novel materials with set electronic, magnetic and optical properties.
1 ex, 1 tbl
Title | Year | Author | Number |
---|---|---|---|
METHOD OF OBTAINING 2,5-DIALKYL-3,4-FULLERO[60]TETRAHYDROTHIOPHEN-1-ONS | 2007 |
|
RU2342377C2 |
METHOD OF OBTAINING 2-ALKYL-5-PHENYL-3,4- FULLERO[60]TETRAHYDROTHIOPHENES | 2007 |
|
RU2342376C2 |
METHOD OF OBTAINING 3,4-FULLERO [60]TETRAHYDROTHIOPHENE | 2007 |
|
RU2342378C2 |
METHOD FOR PREPARING 1-PHENYL-2,5-DIALKYL-3,4-FULLERO[60]PHOSPHOLANES | 2006 |
|
RU2310660C1 |
METHOD OF PRODUCING 2,5-DIALKYL(2,2,5,5-TETRAALKYL)-3,4-FULLERO[60]TETRADIHYDROFURANES | 2008 |
|
RU2371441C1 |
METHOD OF OBTAINING 2,5-DIPHENYL-3,4-FULLERO[60]TETRAHYDROTHIOPHEN-1-ON | 2007 |
|
RU2342380C2 |
METHOD OF OBTAINING 2,5-DIPHENYL-3,4- FULLERO[60]TETRAHYDROTHIOPHEN | 2007 |
|
RU2342379C2 |
METHOD OF OBTAINING 3,4-FULLERO[60]TETRAHYDROTHIOPHEN-1-ON | 2007 |
|
RU2342381C2 |
METHOD FOR PREPARING 1,2,5-TRIALKYL-3,4-FULLERO[60]PHOSPHOLANES | 2006 |
|
RU2315055C1 |
METHOD FOR PREPARING 1-(DIALKOXYMETHYL)-2-HYDRO[60]FULLERENES | 2003 |
|
RU2240302C1 |
Authors
Dates
2008-12-27—Published
2007-02-05—Filed