FIELD: chemistry, pharmacology.
SUBSTANCE: claimed invention relates to field of organic chemistry, namely to method of obtaining 2,5-diphenyl-3,4-fullero[60]tetrahydrothiophen of formula (I) 
. Essence of method lies in interaction of fullerene C60 with dibenzylsulfide in presence of catalyst hafnocene dichloride Cp2HfCl2 in toluol medium at temperature 140-160°C during 4-8 hours. Target product output is 42-64%.
EFFECT: obtaining compound, which can be used as complex-forming agent, sorbent, biologically active compound, as well as in creation of novel materials with set electronic, magnetic and optical properties.
9 ex
| Title | Year | Author | Number |
|---|---|---|---|
| METHOD OF OBTAINING 2,5-DIPHENYL-3,4-FULLERO[60]TETRAHYDROTHIOPHEN-1-ON | 2007 |
|
RU2342380C2 |
| METHOD OF OBTAINING 2,5-DIALKYL-3,4- FULLERO[60]TETRAHYDROTHIOPHENES | 2007 |
|
RU2342382C2 |
| METHOD OF OBTAINING 2,5-DIALKYL-3,4-FULLERO[60]TETRAHYDROTHIOPHEN-1-ONS | 2007 |
|
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| METHOD OF OBTAINING 3,4-FULLERO [60]TETRAHYDROTHIOPHENE | 2007 |
|
RU2342378C2 |
| METHOD OF OBTAINING 3,4-FULLERO[60]TETRAHYDROTHIOPHEN-1-ON | 2007 |
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RU2342381C2 |
| METHOD OF OBTAINING 2-ALKYL-5-PHENYL-3,4- FULLERO[60]TETRAHYDROTHIOPHENES | 2007 |
|
RU2342376C2 |
| METHOD OF PRODUCING 2,3-FULLERO-7-THIABICYCLO [2,2,1]HEPTANE | 2007 |
|
RU2349593C1 |
| METHOD FOR PREPARING 1-(N-PHENYLAMINO)-1,2-DIHYDRO[60]FULLERENE | 2006 |
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RU2310646C1 |
| METHOD FOR PREPARING 1-(6,7-DIMETHOXY-1,2,3,4-TETRAHYDROISOQUINOLINE-2-YLAMINO)-1,2-DIHYDRO[60]FULLERENE | 2006 |
|
RU2309954C1 |
| METHOD OF PRODUCING 1-PHENOXY-1,2-DIHYDRO[60]FULLERENE | 2008 |
|
RU2385859C2 |
