FIELD: chemistry.
SUBSTANCE: invention relates to isoolefin and multiolefin copolymers, copolymer possessing copolymer sequence distribution which is determined by parameter m of copolymer sequence distribution. Method of copolymer obtaining includes contacting of isoolefin, preferably isobutylene, and multiolefin, representing conjugated diene, isoprene, one or more Lewis acids, one or more initiators and thinner that includes one or several fluorohydrocarbons (FHC). As fluorohydrocarbons, one or several fluorohydrocarbons represented by general formula CxHyFz are selected.
EFFECT: reduction of particle agglomeration and reactor contamination without damage to technological parameters, conditions or components and/or without damage to productivity/throughput and/or ability to form highly-molecular polymers.
27 cl, 152 ex, 26 tbl, 4 dwg
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Authors
Dates
2009-01-27—Published
2003-12-19—Filed