FIELD: chemistry.
SUBSTANCE: invention claims method of preparation of catalytic composition applied onto a carrier and acceptable for ethane and/or ethylene oxidation to acetic acid, where catalytic composition applied onto carrier includes catalyst of one or more metal components, on a carrier with aluminium alpha-oxide. Method involves the following stages: (a) preparation of suspension of one or more metal components and aluminium alpha-oxide carrier or carrier precedent particles, (b) dispersion drying of suspension, and optionally (c) calcination of dispersion-dried suspension to obtain catalytic composition applied onto carrier. Invention also claims catalytic composition applied onto carrier and obtained by the claimed method, and method of selective ethane and/or ethylene oxidation to acetic acid using the catalytic composition applied onto carrier.
EFFECT: high selectivity of target products and reduced COX generation.
44 cl, 2 tbl, 1 dwg, 3 ex
| Title | Year | Author | Number | 
|---|---|---|---|
| CATALYST COMPOSITION AND METHOD OF ETHANE AND/OR ETHYLENE SELECTIVE OXIDATION TO ACETIC ACID | 2004 | 
 | RU2362622C2 | 
| METHOD FOR PREPARING ACETIC ACID | 1999 | 
 | RU2233832C2 | 
| FLUIDIZED-BED VINYL ACETATE PRODUCTION CATALYST | 1999 | 
 | RU2237517C2 | 
| METHOD OF OXIDATION IN REACTOR WITH PSEUDOLIQUEFIED LAYER | 2002 | 
 | RU2339611C2 | 
| ETHANE OXIDATION CATALYST AND METHOD WHERE SAID CATALYST IS USED | 2002 | 
 | RU2387478C2 | 
| METHOD OF PREPARING CATALYST CARRIER AND ITS USE IN PRODUCTION OF CATALYSTS | 2006 | 
 | RU2408424C2 | 
| CATALYST FOR OXIDIZING ETHANE AND/OR ETHYLENE INTO ACETIC ACID (OPTIONS) AND ACETIC ACID PRODUCTION METHOD | 1999 | 
 | RU2208480C2 | 
| OXIDATION CATALYST AND A METHOD IMPLEMENTED USING IT | 2000 | 
 | RU2238144C2 | 
| ALKENYL CARBOXYLATE OR ALKYL CARBOXYLATE PRODUCTION PROCESS | 2003 | 
 | RU2315033C2 | 
| OXIDATION METHOD OF PRODUCING CARBOXYLIC ACIDS AND ALKENES AND OPTIONALLY ALKENYLCARBOXYLATE OR ALKYLCARBOXYLATE | 2004 | 
 | RU2356884C2 | 
Authors
Dates
2009-02-20—Published
2003-12-11—Filed