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2 348 602

(13)

(51)

IPC

C07C13/64(2006-01-01)

C07C5/02(2006-01-01)

B01J21/02(2006-01-01)

B01J21/10(2006-01-01)

B01J21/06(2006-01-01)

B01J31/14(2006-01-01)

(21) (22)

Application

2007128195/04, 2007-07-23

(24)

Start date

2007-07-23

(22)

Actual filing date

2007-07-23

(45)

Published

2009-03-10

(72)

Inventor

Dzhemilev Usein MemetovichTuktarov Ajrat RamilevichAkhmetov Arslan RifkhatovichD'Jakonov Vladimir Anatol'EvichIbragimov Askhat Gabdrakhmanovich

(73)

Holder

Institut Neftekhimii I Kataliza Ran

METHOD OF OBTAINING POLYHYDRO[60]FULLERENES Russian patent published in 2009 - IPC C07C13/64 C07C5/02 B01J21/02 B01J21/10 B01J21/06 B01J31/14

Abstract RU 2348602 C1

FIELD: chemistry.

SUBSTANCE: invention concerns method of obtaining polyhydro[60]fullerenes of formula (1): , involving fullerene C₆₀ interaction with diethylaluminium chloride (Et₂AlCl) in the presence of magnesium powder and titanocene dichloride catalyst (Cp₂TiCl₂) at molar ratio of C₆₀:Et₂AlCl:Mg:Cp₂TiCl₂=1:(110-130):(55-65):(0.15-0.25), preferably 1:120:60:0.20, in argon atmosphere in the absence of light at room temperature of (20-21°C) and atmospheric pressure in toluene and tetrahydrofuran medium for 1-3 hours, with further hydrolysis of reaction mass. The method allows obtaining total 70-88% output of polyhydro[60]fullerene after reaction mass hydrolysis.

EFFECT: improved method.

9 ex, 1 tbl

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RU 2 348 602 C1

Authors

Dzhemilev Usein Memetovich

Tuktarov Ajrat Ramilevich

Akhmetov Arslan Rifkhatovich

D'Jakonov Vladimir Anatol'Evich

Ibragimov Askhat Gabdrakhmanovich

Dates

2009-03-10—Published

2007-07-23—Filed