Show metadata Hide metadata

(19)

(11)

2 348 604

(13)

(51)

IPC

C07C13/64(2006-01-01)

C07C5/02(2006-01-01)

B01J21/10(2006-01-01)

B01J21/02(2006-01-01)

B01J21/06(2006-01-01)

B01J31/14(2006-01-01)

(21) (22)

Application

2007128184/04, 2007-07-23

(24)

Start date

2007-07-23

(22)

Actual filing date

2007-07-23

(45)

Published

2009-03-10

(72)

Inventor

Dzhemilev Usein MemetovichTuktarov Ajrat RamilevichAkhmetov Arslan RifkhatovichKhafizova Lejla OsmanovnaD'Jakonov Vladimir Anatol'EvichIbragimov Askhat Gabdrakhmanovich

(73)

Holder

Institut Neftekhimii I Kataliza Ran

METHOD OF OBTAINING POLYHYDRO[60]FULLERENES Russian patent published in 2009 - IPC C07C13/64 C07C5/02 B01J21/10 B01J21/02 B01J21/06 B01J31/14

Abstract RU 2348604 C1

FIELD: chemistry.

SUBSTANCE: invention concerns method of obtaining polyhydro[60]fullerenes of formula (1): , involving fullerene C₆₀ interaction with ethylaluminium dichloride (EtAlCl₂) in the presence of magnesium powder and titanocene dichloride catalyst (Cp₂TiCl₂) at molar ratio of C₆₀:EtAlCl₂:Mg:Cp₂TiCl₂=1:(55-65):(55-65):(0.15-0.25), preferably 1:60:60:0.20, in argon atmosphere in the absence of light at room temperature of (20-21°C) and atmospheric pressure in toluene and tetrahydrofuran medium for 1-3 hours, with further hydrolysis of reaction mass. The method allows obtaining 72-86% output of polyhydro[60]fullerene after reaction mass hydrolysis.

EFFECT: improved method.

1 tbl, 7 ex

Similar patents RU2348604C1

Title	Year	Author	Number
METHOD OF OBTAINING POLYHYDRO[60]FULLERENES	2007	Dzhemilev Usein Memetovich Tuktarov Ajrat Ramilevich Akhmetov Arslan Rifkhatovich D'Jakonov Vladimir Anatol'Evich Ibragimov Askhat Gabdrakhmanovich	RU2348602C1
METHOD FOR PREPARING 1-[1'-HYDROXY-1'-ALKYL-(1',1'-DIALKYL)]-METHYL-2-HYDRO[60]FULLERENES	2003	Dzhemilev U.M. Ibragimov A.G. Khafizova L.O. Borisova A.L. Tuktarov R.F. Abzalimov R.R. Khalilov L.M.	RU2238263C1
METHOD FOR PREPARING 1-[1-HYDROXY-1-(PYRID-4-YL)METHYL]-1,2-DIHYDRO[60]FULLERENES	2005	Dzhemilev Usein Memetovich Ibragimov Askhat Gabdrakhmanovich Khafizova Lejla Osmanovna Makhamatkhanova Alevtina Leonidovna Dzhmileva Galina Arkad'Evna Muradymova Svetlana Maratovna	RU2294928C2
METHOD FOR PREPARING 1-(DIALKOXYMETHYL)-2-HYDRO[60]FULLERENES	2003	Dzhemilev U.M. Ibragimov A.G. Dekhtjar' E.F. Tuktarov R.F. Abzalimov R.R. Khalilov L.M.	RU2240302C1
METHOD OF PREPARING 1-ETHYL-2,3-FULLERENE [60] ALUMACYCLOPROPANES	1999	Dzhemilev U.M. Ibragimov A.G. Khafizova L.O. Chegodaeva M.F. Tomilov Ju.V. Nefedov O.M.	RU2160272C1
METHOD OF PREPARING 1-ALKOXY-2,3-FULLERENE [60] ALUMACYCLOPROPANES	1999	Dzhemilev U.M. Ibragimov A.G. Khafizova L.O. Nikitina E.V. Tomilov Ju.V. Nefedov O.M.	RU2160274C1
METHOD OF PREPARING 1-DIALKYLAMINE-2,3-FULLERENE [60] ALUMACYCLOPROPANES	1999	Dzhemilev U.M. Ibragimov A.G. Khafizova L.O. Nikitina E.V. Gil'Fanova G.N. Abzalimov R.R.	RU2160271C1
METHOD OF OBTAINING POLYHYDRO[60]FULLERENES	2007	Dzhemilev Usein Memetovich Tuktarov Ajrat Ramilevich Akhmetov Arslan Rifkhatovich D'Jakonov Vladimir Anatol'Evich Ibragimov Askhat Gabdrakhmanovich	RU2348605C1
METHOD OF OBTAINING POLYHYDRO[60]FULLERENES	2007	Dzhemilev Usein Memetovich Tuktarov Ajrat Ramilevich Akhmetov Arslan Rifkhatovich D'Jakonov Vladimir Anatol'Evich Ibragimov Askhat Gabdrakhmanovich	RU2348601C1
METHOD OF OBTAINING POLYHYDRO[60]FULLERENES	2007	Dzhemilev Usein Memetovich Tuktarov Ajrat Ramilevich Akhmetov Arslan Rifkhatovich D'Jakonov Vladimir Anatol'Evich Ibragimov Askhat Gabdrakhmanovich	RU2348603C1

RU 2 348 604 C1

Authors

Dzhemilev Usein Memetovich

Tuktarov Ajrat Ramilevich

Akhmetov Arslan Rifkhatovich

Khafizova Lejla Osmanovna

D'Jakonov Vladimir Anatol'Evich

Ibragimov Askhat Gabdrakhmanovich

Dates

2009-03-10—Published

2007-07-23—Filed