FIELD: chemistry.
SUBSTANCE: invention can be used in nuclear technology. Uranium oxides with valency from +4 to +6 undergo the reaction with hydrogen fluoride forming the intermediate containing 40÷80 wt % of uranylfluoride or uranium tetrafluoride, the rest is initial products. Then obtained intermediate product is directed to flame reactor for fluorination by elemental fluorine taken in the excess 5÷7 %. The obtained uranium hexafluoride is separated from gas phase by desublimation. The fluorine-containing products remaining in the gas phase after desublimation are taken for entrapment by the initial uranium oxides.
EFFECT: invention allows to enhance the process efficiency and obtain uranium hexafluoride of 99,9% purity.
1 tbl
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Authors
Dates
2009-05-20—Published
2007-12-19—Filed