FIELD: chemistry.
SUBSTANCE: initial gas-flow passes the first ammonia oxidation stage containing the catalyst (the metal of platinum group with large surface area) whereat it is converted with the yield 20 - 99% to the nitrogen oxides. Then the gas mix containing the nitrogen oxides, oxygen and unreacted ammonia pass the second ammonia oxidation stage containing the catalyst promoting as well the destruction of N2O. The second stage products contain the traces of unreacted ammonia and less than 500 ppm of N2O. The process is carried out at temperature range 700 - 1000°C. The method of catalyst download for the implementation of aforementioned process is claimed. The preferable implementation versions allow obtaining of the low N2O yields and increasing of the catalyst operating life.
EFFECT: high ammonia conversion, low yield of N2O, performance improving at startup and shutdown of the process, lower consumption of the platinum group metals and increasing of the catalyst operating life.
11 cl, 1 tbl, 1 dwg, 11 ex
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Authors
Dates
2009-06-20—Published
2004-04-27—Filed