FIELD: chemistry.
SUBSTANCE: method involves drying crushed slate, thermal decomposition using solid heat carrier obtaining a vapour-gas mixture, removal of mechanical impurities from the latter, extraction resin fractions with boiling point above 175°C from the vapour-gas mixture, cooling the remaining vapour-gas mixture with its division into low-temperature coking gas, pyroligneous liquor and a gasoline fraction with boiling point below 175°C, distillation of the latter with successive extraction of three fractions with boiling points 79 to 90°C, 90 to 116°C and 116 to 145°C, extractive rectification of each of the three fractions in the presence of the same solvent - mixture of N-formylmorpholine and propylenecarbonate with subsequent extraction of thiophene, methylthiophenes and dimethyl-thiophenes from each fraction, respectively.
EFFECT: design of a method for thermal processing high-sulphur slate, which allows for obtaining valuable target chemical substances from the thiophene family, with cost effective and efficient processing of high-sulphur slate.
1 dwg, 3 ex
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Authors
Dates
2009-10-27—Published
2008-06-30—Filed