FIELD: chemistry.
SUBSTANCE: present invention describes an arylphenoxy catalyst system for producing a homopolymer of ethylene and copolymers and alpha-olefins, and a method of producing homopolymer of ethylene and copolymers and alpha-olefins, with high molecular weight under polymerisation conditions for a solution at high temperature using the same catalyst. The catalyst system contains a catalyst based on arylphenoxy-substituted group 4 transition metal and aluminoxane co-catalyst from a boron compound. In the transition metal catalyst, a cyclopentadiene derivative and arylphenoxide as chemically bonded ligands are localised around the group 4 transition metal. The arylphenoxide ligand is substituted with at least one aryl derivative and is localised in its ortho position and the ligands are linked with each other.
EFFECT: catalyst contains environmentally friendly material, its synthesis is cheap, and has excellent thermal stability; the catalyst is used in production of homopolymer of ethylene and copolymers and alpha-olefins with different physical properties in industrial polymerisation processes.
14 cl, 20 ex
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Authors
Dates
2009-11-27—Published
2005-10-14—Filed