ARYLPHENOXY CATALYST SYSTEM FOR PRODUCING HOMOPOLYMER OR COPOLYMERS OF ETHYLENE AND ALPHA-OLEFINS Russian patent published in 2009 - IPC C08F10/02 C08F4/64 B01J31/12 

Abstract RU 2374267 C2

FIELD: chemistry.

SUBSTANCE: present invention describes an arylphenoxy catalyst system for producing a homopolymer of ethylene and copolymers and alpha-olefins, and a method of producing homopolymer of ethylene and copolymers and alpha-olefins, with high molecular weight under polymerisation conditions for a solution at high temperature using the same catalyst. The catalyst system contains a catalyst based on arylphenoxy-substituted group 4 transition metal and aluminoxane co-catalyst from a boron compound. In the transition metal catalyst, a cyclopentadiene derivative and arylphenoxide as chemically bonded ligands are localised around the group 4 transition metal. The arylphenoxide ligand is substituted with at least one aryl derivative and is localised in its ortho position and the ligands are linked with each other.

EFFECT: catalyst contains environmentally friendly material, its synthesis is cheap, and has excellent thermal stability; the catalyst is used in production of homopolymer of ethylene and copolymers and alpha-olefins with different physical properties in industrial polymerisation processes.

14 cl, 20 ex

Similar patents RU2374267C2

Title Year Author Number
MODERN CATALYTIC SYSTEMS WITH TRANSITION METAL BASED ON COMONOMER INCORPORATION AND METHODS FOR PREPARING ETHYLENE HOMOPOLYMERS OR COPOLYMERS OF ETHYLENE AND OLEFINS USING THEM 2011
  • Li Kho Seong
  • Khakhn Dzong Sok
  • Shin Dong Cheol
  • Li Khio Sun
  • Vu Chun Dzi
RU2575004C2
TRANSITION METAL BASED CATALYST SYSTEMS AND METHODS OF PRODUCING HOMOPOLYMERS OF ETHYLENE OR COPOLYMERS OF ETHYLENE AND α-OLEFINS USING SAID SYSTEMS 2009
  • Ok Miungakhn
  • Shin Dongcheol
  • Dzeong Dzisu
  • Li Khoseong
  • Khan Dzongsok
  • Shim Choonsik
RU2507210C2
METHOD OF OBTAINING ELASTIC COPOLYMERS OF ETHYLENE AND ALPHA-OLEFINS 2009
  • Ok Miungakhn
  • Shin Daekho
  • Kvon Seungbum
  • Khan Dzongsok
  • Li Khoseong
  • Shim Choonsik
  • Kham Khieongtaek
  • Dzeong Dzisu
  • Chae Sungseok
RU2512536C2
NEW TETRAARYLBORATE COMPOUND INCLUDING ITS CATALYTIC COMPOSITION AND METHOD FOR PRODUCING ETHYLENE HOMOPOLYMERS OR ETHYLENE AND α-OLEFIN COPOLYMERS USING IT 2020
  • Shin, Dongcheol
  • Oh, Yeonock
  • Kim, Miji
RU2801287C2
ETHYLENE COPOLYMER AND METHOD OF PRODUCING SAID COPOLYMER 2009
  • Shin Daekho
  • Shim Choonsik
  • Dzeong Dzisu
  • Chae Sungseok
  • Ok Miungakhn
  • Kvon Seungbum
  • Shin Dongcheol
  • Li Khoseong
RU2468039C2
NOVEL METALLOCENE COMPOUND, CATALYTIC COMPOSITION CONTAINING THEREOF AND METHOD OF OBTAINING OLIFIN-BASED POLYMERS WITH ITS APPLICATION 2012
  • Kim Se-Jung
  • Cho Min-Sok
  • Nechaev Mikhail Sergeevich
  • Li Ki-Su
  • Li Jong-Kho
  • Cho Kjung-Chin
  • Li Sung-Min
  • Bush Aleksandr Alekseevich
  • Li Min-Chon
  • Khokhlov Aleksej Removich
  • Asachenko Andrej Fedorovich
  • Dzhevakov Pavel Borisovich
  • Morozov Oleg Sergeevich
  • Valeeva Julija Kamil'Evna
  • Smirnov Aleksandr Jur'Evich
RU2529020C2
OLEFIN BASED POLYMER WITH EXCELLENT PROCESSING ABILITY 2015
  • Kim Joong Soo
  • Lee Ki Soo
  • Hong Dae Sik
  • Song Ki Heon
  • Song Eun Kyoung
  • Kwon Heon Yong
  • Lee Yong Ho
  • Jeong Dong Hoon
  • Sun Soon Ho
  • Kim Sun Mi
  • Sung Yu Taek
RU2670752C9
ETHYLENE/ALPHA-OLEFIN COPOLYMERS, CHARACTERIZED BY EXCELLENT PROCESSABILITY 2015
  • Kim Dzoong Soo
  • Sun Soon Kho
  • Kvon Okh Dzoo
  • Choj I Yang
  • Li Ki Soo
RU2671499C1
METHOD OF PRODUCING ETHYLENE-α-OLEFIN-DIENE COPOLYMER 2012
  • Shin Dong Cheol
  • Li Kho Seong
  • Kim Seong Kiun
  • Li Sang Ik
  • Kim Sun Yang
  • Khakhn Dzong Sok
  • Dzeon Chan Voong
  • Kim Dzeong Khvan
RU2599626C2
HIGHLY ACTIVE AND HIGHLY SELECTIVE CATALYST OF ETHYLENE OLIGOMERISATION AND METHOD OF OBTAINING HEXENE OR OCTENE WITH APPLICATION OF SAID CATALYST 2010
  • Khan Tak-Kiu
  • Kang Sang-Ook
  • Kim Sung-Kvan
RU2541528C2

RU 2 374 267 C2

Authors

Vu Teh Vu

Ok M'Jung An

Khan Dzhong Sok

Li Mal U.

Kang Sang Ook

Ko Sung Bo

Kim Teh Dzhin

Kim Sung Kvan

Dates

2009-11-27Published

2005-10-14Filed