FIELD: chemistry.
SUBSTANCE: claimed invention relates to novel metallocene compound, catalytic composition, which includes said compound, and method of obtaining olefin-based polymers with application of said composition. Metallocene compound is represented below by formula 1 , in which R1 and R2 are similar or different from each other and independently represent hydrogen, C1~C20 - alkyl group, C1~C20 - alkoxygroup, C2~C20 - alkenyl group, C6~C20 - aryl group, C7~C20 - alkylaryl group, C7~C20 - arylalkyl group or C7~C20 - alkoxyaryl group; R3 represents C1~C20 - alkylsilyl group; Q1 and Q2 are similar or different from each other and independently represent hydrogen, C1~C20 - alkyl group or halogen; and M represents Zr, Ti or Hf.
EFFECT: application of novel metallocene compound as catalyst for obtaining olefin-based polymers provides possibility of synthesising olefin-based polymer, having low molecular weight and wide molecular-weight distribution.
7 cl, 1 tbl, 8 ex
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Authors
Dates
2014-09-27—Published
2012-10-17—Filed