FIELD: chemistry.
SUBSTANCE: invention relates to a method of inhibiting polymerisation of styrene in the presence of an inhibitor at 120±5°C, which is characterised by that, the process is carried out in the presence of an inhibitor which contains N,N-dimethyl-3,5-di-tert-butyl-4-hydroxybenzylamine, saturated carboxylic acid and unsaturated carboxylic acid, with the ratio of components N,N-dimethyl-3,5-di-tert-butyl-4-hydroxybenzylamine:saturated carboxylic acid:unsaturated carboxylic acid equal to (1-2):(0.5-1.8):(0.1-1.4) pts. wt, respectively.
EFFECT: efficient prevention of polymerisation of styrene due to reduced amount of thermopolymer from 1,13 wt % to 0 wt % formed with less consumption of inhibitor in amount of 0,05 wt %.
1 tbl
Title | Year | Author | Number |
---|---|---|---|
STYRENE POLYMERISATION INHIBITOR COMPOSITION | 2008 |
|
RU2391327C2 |
PROCESS FOR INHIBITING POLYMERIZATION OF VINYL AROMATIC MONOMERS | 1992 |
|
RU2046804C1 |
COMPOSITION FOR INHIBITING OF STYRENE THERMOPOLYMERIZATION AND METHOD FOR PRODUCTION THEREOF | 2005 |
|
RU2290394C1 |
INHIBITING STYRENE THERMOPOLYMERIZATION COMPOSITION | 1998 |
|
RU2149153C1 |
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RU2826445C1 |
USE OF POLYGLYCEROL ESTERS AS TRIBO-MODIFIERS IN LUBRICATING COMPOSITIONS | 2016 |
|
RU2726194C2 |
METHOD OF INHIBITING THERMAL POLYMERIZATION OF STYRENE | 0 |
|
SU763313A1 |
METHOD OF INHIBITING STYRENE POLYMERIZATION | 0 |
|
SU1139722A1 |
POLYMER COMPOSITION WITH ANTISTATIC FINISHING, METHOD OF PREPARING THEREOF AND COMPOSITION FOR ANTISTATIC FINISHING | 1997 |
|
RU2161635C2 |
INHIBITING COMPOSITION FOR STYRENE THERMOPOLYMERIZATION | 1998 |
|
RU2152377C1 |
Authors
Dates
2009-12-10—Published
2008-06-18—Filed