FIELD: chemistry.
SUBSTANCE: invention relates to a method of producing 1-(2-propenyloxy)- or 1-(phenylmethoxy)-1,2-dihydro[60]fullerene of general formula (1) 
, which can be used as complexing agents, sorbents, biologically active compounds, as well as in making new materials with given properties. The method involves reacting fullerene C60 with allyl or benzyl alcohol in the presence of a titanocene dichloride catalyst in molar ratio C60 : R-CH2-OH : Cp2TiCl2 equal to 0.01 : (5-10) : (0.0015-0.0025), in a toluene medium as a solvent at temperature ranging from 70 to 90°C for 3 to 7 hours.
EFFECT: method allows for selective production of end products with high output 62-80%.
1 tbl, 1 ex
| Title | Year | Author | Number |
|---|---|---|---|
| METHOD OF PRODUCING 1-ALKOXY- OR 1-CYCLOALKOXY-1,2-DIHYDRO[60]FULLERENE | 2008 |
|
RU2384561C2 |
| METHOD OF OBTAINING 3,4-FULLERO [60]TETRAHYDROTHIOPHENE | 2007 |
|
RU2342378C2 |
| METHOD OF PRODUCING 2,5-DIALKYL(2,2,5,5-TETRAALKYL)-3,4-FULLERO[60]TETRADIHYDROFURANES | 2008 |
|
RU2371441C1 |
| METHOD OF PRODUCING 1-PHENOXY-1,2-DIHYDRO[60]FULLERENE | 2008 |
|
RU2385859C2 |
| METHOD OF PRODUCING 1-HYDROXY-1,2-DIHYDRO[60]FULLERENE | 2007 |
|
RU2349575C1 |
| METHOD FOR PREPARING 1-(4-QUINOLINAMINO)-1,2-DIHYDRO[60]FULLERENE | 2006 |
|
RU2313521C1 |
| METHOD FOR PREPARING 1-{[1-(HYDROXYMETHYL)PROPYL]AMINO}-1,2-DIHYDRO[60]FULLERENE | 2006 |
|
RU2309938C1 |
| METHOD OF OBTAINING 2,5-DIALKYL-3,4-FULLERO[60]TETRAHYDROTHIOPHEN-1-ONS | 2007 |
|
RU2342377C2 |
| METHOD FOR PREPARING 1-(N,N-DIPROP-2-ENYLAMINO)-1,2-DIHYDRO[60]FULLERENE | 2006 |
|
RU2309939C1 |
| METHOD FOR PREPARING 1-(N,N-DIPHENYLAMINO)-1,2-DIHYDRO[60]FULLERENE | 2006 |
|
RU2309941C1 |
