FIELD: organic chemistry, chelating agents, chemical technology.
SUBSTANCE: invention relates to a method for synthesis of 1-(N,N-diphenylamino)-1,2-dihydro[60]fullerene of the formula (I): 
. Method involves interaction of fullerene-C60 with diphenylamine (Ph2NH) in the mole ratio fullerene-C60 : diphenylamine = 0.01:(0.01-0.011) in the presence of titanocene dichloride (Cp2TiCl2) as a catalyst taken in the amount 15-25 mol.% with respect to fullerene-C60 in toluene medium as a solvent, at temperature 140-160°C for 8-10 h. The yield of the end product is 64-86%. Synthesized compound can be used as chelating agents, sorbents and biologically active compounds, and in creature of novel materials with desired electronic, magnetic and optical properties.
EFFECT: improved method of synthesis.
1 tbl, 1 ex
| Title | Year | Author | Number |
|---|---|---|---|
| METHOD FOR PREPARING 1-{[1-(HYDROXYMETHYL)PROPYL]AMINO}-1,2-DIHYDRO[60]FULLERENE | 2006 |
|
RU2309938C1 |
| METHOD FOR PREPARING 1-(4-QUINOLINAMINO)-1,2-DIHYDRO[60]FULLERENE | 2006 |
|
RU2313521C1 |
| METHOD FOR PREPARING 1-(N,N-DIPROP-2-ENYLAMINO)-1,2-DIHYDRO[60]FULLERENE | 2006 |
|
RU2309939C1 |
| METHOD FOR PREPARING 1,2,5-TRIALKYL-3,4-FULLERO[60]PHOSPHOLANES | 2006 |
|
RU2315055C1 |
| METHOD FOR PREPARING 1-PHENYL-2,5-DIALKYL-3,4-FULLERO[60]PHOSPHOLANES | 2006 |
|
RU2310660C1 |
| METHOD FOR PRODUCTION OF N,N,1-TRIMETHYL-2-(3,4-FULLERO[60])PYRROLIDINE AMINE | 2005 |
|
RU2283834C1 |
| METHOD FOR PREPARING 1-(N-PHENYLAMINO)-1,2-DIHYDRO[60]FULLERENE | 2006 |
|
RU2310646C1 |
| METHOD FOR PRODUCTION OF 5-METHYL-2,3-FULLERO[60]PIPERAZINE | 2006 |
|
RU2307832C1 |
| METHOD FOR PREPARING 2-(1-METHYL-2-(3,4-FULLERO[60]-PYRROLIDINYL)PHENOL | 2005 |
|
RU2283302C1 |
| METHOD FOR PREPARING 1-(N,N-DICYCLOHEXYLAMINO)-1,2-DIHYDRO[60]FULLERENE | 2006 |
|
RU2310645C1 |
