FIELD: chemistry.
SUBSTANCE: present invention relates to a method of producing 1-phenoxy-1,2-dihydrofullerene of formula (1) 
which can be used as a complexing agent, sorbent, biologically active compound, as well as in making new materials with given electronic, magnetic and optical properties. The method involves reacting fullerene C60 with phenol in the presence of a hafnocene dichloride catalyst in molar ratio C60: Ph-OH:Cp2HfCl2 equal to 0.01:(5-10):(0.0015-0.0025), in a toluene medium as a solvent at temperature 130-180°C for 5-7 hours.
EFFECT: method enables selective production of the end product with output of 63-88%.
1 tbl, 1 ex
| Title | Year | Author | Number |
|---|---|---|---|
| METHOD FOR PREPARING 1-(N-PHENYLAMINO)-1,2-DIHYDRO[60]FULLERENE | 2006 |
|
RU2310646C1 |
| METHOD OF PRODUCING 1-(2-PROPENYLOXY)- OR 1-(PHENYLMETHOXY)-1,2-DIHYDRO[60]FULLERENE | 2008 |
|
RU2375343C2 |
| METHOD OF PRODUCING 2,3-FULLERO-7-THIABICYCLO [2,2,1]HEPTANE | 2007 |
|
RU2349593C1 |
| METHOD OF OBTAINING 2,5-DIPHENYL-3,4-FULLERO[60]TETRAHYDROTHIOPHEN-1-ON | 2007 |
|
RU2342380C2 |
| METHOD OF OBTAINING 2,5-DIPHENYL-3,4- FULLERO[60]TETRAHYDROTHIOPHEN | 2007 |
|
RU2342379C2 |
| METHOD OF PRODUCING 1-ALKOXY- OR 1-CYCLOALKOXY-1,2-DIHYDRO[60]FULLERENE | 2008 |
|
RU2384561C2 |
| METHOD FOR PREPARING 1-(6,7-DIMETHOXY-1,2,3,4-TETRAHYDROISOQUINOLINE-2-YLAMINO)-1,2-DIHYDRO[60]FULLERENE | 2006 |
|
RU2309954C1 |
| METHOD OF PRODUCING 2,5-DIALKYL(2,2,5,5-TETRAALKYL)-3,4-FULLERO[60]TETRADIHYDROFURANES | 2008 |
|
RU2371441C1 |
| METHOD OF PRODUCING 1'(2')a-HOMO(C-I)[5,6]FULLERENE | 2009 |
|
RU2417208C2 |
| METHOD FOR COMBINED SYNTHESIS OF (C-I)[5,6]FULLERO[2',3':1,9]CYCLOPROPANE AND 1Т(2')a-HOMO(C-I)[5,6]FULLERENE | 2009 |
|
RU2409546C2 |
