FIELD: chemistry.
SUBSTANCE: invention relates to a method of inhibiting corrosion in oil refining processes, and is particularly aimed at inhibiting corrosion caused by naphthenic acids. The invention relates to a method of inhibiting corrosion of inner metal surfaces of equipment used in refining crude oil or high-temperature distillates, which are heated to temperature between approximately 350°F and approximately 790°F. The method involves mixing crude oil or high-temperature oil distillate with a corrosion inhibiting amount of corrosion inhibitor, which is selected from a group from (I) and (II) and their mixtures, where the said corrosion inhibitor (I) has formula:  in which W, X, Y and Z are all present and can be identical or different and are separately selected from a group consisting of (OH), (COOH) and COOR1, under the condition that, adjacent pairs of W, X, Y and Z can be selected from
 in which W, X, Y and Z are all present and can be identical or different and are separately selected from a group consisting of (OH), (COOH) and COOR1, under the condition that, adjacent pairs of W, X, Y and Z can be selected from  ; R1 is an alky group with approximately 1 to approximately 16 carbon atoms; and Ar is an aromatic compound; and the said corrosion inhibitor (II) has formula:
; R1 is an alky group with approximately 1 to approximately 16 carbon atoms; and Ar is an aromatic compound; and the said corrosion inhibitor (II) has formula:  , in which R2 and R3 are COOR5,
, in which R2 and R3 are COOR5,  or
 or  under the condition that, when one of R2 and R3 is
under the condition that, when one of R2 and R3 is  or
 or  , then the other is either
, then the other is either  or
 or  , sufficient for formation of an anhydride group which links functional groups R2 and R3; each R5 is independently selected from alkyl groups with approximately 1 to approximately 16 carbon atoms; R4 is COOR6, where R6 is an alkyl group with approximately 1 to approximately 16 carbon atoms; when refining crude oil or high-temperature distillates obtained from the crude oil at high temperature, containing (I) tetrafunctional substituted aromatic compounds and (II) trimellitic acid anhydride ethers.
, sufficient for formation of an anhydride group which links functional groups R2 and R3; each R5 is independently selected from alkyl groups with approximately 1 to approximately 16 carbon atoms; R4 is COOR6, where R6 is an alkyl group with approximately 1 to approximately 16 carbon atoms; when refining crude oil or high-temperature distillates obtained from the crude oil at high temperature, containing (I) tetrafunctional substituted aromatic compounds and (II) trimellitic acid anhydride ethers.
EFFECT: effective reduction of corrosion of metal surfaces when in contact with high-temperature crude oil.
10 cl, 6 ex
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Authors
Dates
2009-12-27—Published
2005-10-25—Filed