FIELD: chemistry.
SUBSTANCE: invention relates to drying hydrocarbons through sorption and can be used in oil refining and petrochemical industries. A calcium chloride based sorbent is proposed, which is placed in pores of a solid body - matrix, which is a composition of aluminium, calcium and boron oxides, with the following content of components of the sorbent, wt %: AI2O3 - 50-80; B2O3 -5-30; CaO - 10-11; CaCl2 - 5-30, with total concentration of Broensted and Lewis acid sites on the surface of the sorbent of not more than 7 mcmol/g. The sorbent for drying hydrocarbons is obtained by simultaneously mixing a hydrate of aluminium oxide with pseudo-boehmite structure with orthoboric acid and calcium chloride, granulation, drying and calcination. The method of drying hydrocarbons involves bringing hydrocarbons into contact with the proposed sorbent at temperature 0-40°C and regeneration of the sorbent at temperature 150-200°C in the current of a gas consisting of C1-C4 hydrocarbons, hydrogen, nitrogen.
EFFECT: invention enables efficient drying of hydrocarbons, particularly pyrolysis gas; the sorbent is characterised by high stability of drying properties during repeated use in drying-regeneration cycles.
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Authors
Dates
2010-01-20—Published
2006-02-09—Filed