FIELD: chemistry.
SUBSTANCE: described is a method of producing norbornene addition polymers (bicycle[2.2.1]heptene-2)through polymerisation of norbornene in the presence of a catalyst system obtained by reacting a palladium cationic complex in an organic solvent and etharate of boron trifluoride of formula BF3OEt2, distinguished by that the palladium complex used is tetrafluoroborate acetylacetonatobis(triarylphosphine) palladium with general formula [(Acac)Pd(PR3)2]BF4, where Acac is acetylacetonate, where R=o-tolyl, n - tolyl, phenyl. The process is carried out in molar ratio of boron to palladium B:Pd=5:1-40:1 and temperature 15-70°C.
EFFECT: increased efficiency of norbornene polymerisation process through increased catalyst activity.
4 tbl, 18 ex
| Title | Year | Author | Number |
|---|---|---|---|
| METHOD OF POLYMERIZATION OF NORBORENE IN PRESENCE OF ANILINE COMPLEXES OF PALLADIUM | 2015 |
|
RU2641690C2 |
| METHOD FOR ADDITION POLYMERISATION OF NORBORNENE | 2014 |
|
RU2570703C1 |
| METHOD FOR PREPARING CATALYST FOR POLYMERIZATION OF NORBORNENE | 2006 |
|
RU2315064C1 |
| METHOD OF ADDITIVE POLYMERIZATION OF NORBORNEN AND ITS DERIVATIVES | 2015 |
|
RU2626745C2 |
| METHOD OF PREPARING CATALYST FOR POLYMERISATION OF NORBORNENE | 2009 |
|
RU2414965C1 |
| METHOD FOR ADDITION POLYMERISATION OF NORBORNENE | 2012 |
|
RU2487896C1 |
| METHOD FOR ADDITIVE COPOLYMERIZATION OF NORBORNENE WITH 5-METHOXYCARBONYLNORBORNENE | 2017 |
|
RU2653060C1 |
| METHOD FOR ADDITION POLYMERISATION OF NORBORNENE | 2012 |
|
RU2487895C1 |
| METHOD OF PREPARING CATALYST FOR OLIGOMERIZATION OF STYRENE | 2005 |
|
RU2290995C1 |
| METHOD OF OBTAINING DIFFERENT-LIGAND CATIONIC COMPLEXES OF PALLADIUM | 2009 |
|
RU2423373C1 |
