FIELD: chemistry.
SUBSTANCE: polyester-ketone is obtained by reacting potassium diphenolate with 4,4'-dichlorobenzophenone in dimethylsulfoxide at 160-170°C for 4 hours. Subsequent precipitation in isopropyl alcohol and drying to constant mass of the obtained oligomer with degree of condensation equal to 20 is carried out. Further, the oligomer is converted to a dipotassium salt by reacting with an alkaline solution and reaction with 4,4'-difluorobenzophenone is carried out at 170-300°C in an organic solvent medium for 6 hours.
EFFECT: shorter synthesis time and obtaining a cheap end product with high output while using a cheap monomer.
2 cl, 2 ex
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Authors
Dates
2010-03-10—Published
2008-02-26—Filed