FIELD: chemistry.
SUBSTANCE: invention relates to methods of obtaining weakly acidic carboxylic cationites used in sorption processes in hydrometallurgy, biotechnology and heat engineering. A method is described for obtaining carboxylic cationites through suspension copolymerisation of acrylonitrile, divinylbenzene and methacrylic acid in the presence of a blowing agent and a polymerisation initiator - benzoyl peroxide in a medium of a water-salt solution of potato starch containing 20% sodium or ammonium chloride, or in a medium of an aqueous solution of cellulose, with subsequent alkaline hydrolysis of nitrile groups of the copolymer, with 71-76.5% acrylonitrile, 8-12% divinylbenzene, 5-10% methacrylic acid content in the polymerisation mixture and using a blowing agent in form of butylacetate in amount of 15-40% of the volume of the mixture of monomers.
EFFECT: design of an efficient method of obtaining weakly acidic carboxylic cationites.
4 ex, 1 tbl
Title | Year | Author | Number |
---|---|---|---|
METHOD OF OBTAINING CARBOXYLIC CATION EXCHANGE RESIN | 2006 |
|
RU2326130C1 |
0 |
|
SU448193A1 | |
METHOD FOR SYNTHESIS OF POROUS WEAKLY BASIC ANIONITES | 2008 |
|
RU2387673C1 |
METHOD FOR ION EXCHANGER PREPARATION FOR GOLD SORPTION | 2016 |
|
RU2615522C1 |
METHOD OF PRODUCING EASILY REGENERATED IONITE | 2012 |
|
RU2493915C1 |
METHOD OF PREPARING MICROSHERICAL CARBOXYL CATIONITES | 1992 |
|
RU2045539C1 |
METHOD FOR PREPARATION OF LOW-BASIC ANIONITES | 2006 |
|
RU2323944C1 |
METHOD FOR OBTAINING ANIONITES | 0 |
|
SU1657513A1 |
METHOD OF PREPARING SPHERICAL POLYMER PARTICLES | 0 |
|
SU566849A1 |
METHOD OF PREPARING CARBOXYLIC CATION-EXCHANGE RESIN | 0 |
|
SU806690A1 |
Authors
Dates
2010-06-10—Published
2008-09-30—Filed