METHOD FOR SYNTHESIS OF POROUS WEAKLY BASIC ANIONITES Russian patent published in 2010 - IPC C08F220/44 C08F212/36 

Abstract RU 2387673 C1

FIELD: chemistry.

SUBSTANCE: proposed is a method for synthesis of porous weakly-basic anionites through copolymerisation of acrylonitrile and divinylbenzene in the presence of blowing agents and a benzoperoxide polymerisation initiator, with subsequent aminolysis of the copolymers with polyamines with an elementa-y sulphur catalyst, where acrylonitrile and divinylbenzene are copolymerised at pressure 1.2-2.7 atm with addition into the polymerisation mixture of unsaturated compounds selected from a group comprising acrylic esters, styrene, methyl- and ethylstyrene, with content of acrylonitrile not less than 67.5 mol %, divinybenzene 8-20 % and molar ratio of acrylonitrile to the rest of the unsaturated components not greater than 2.5:1, and aminolysis is carried out with triethylene tetramine and diethylene triamine in the presence of 0.1-0.5 % elementary sulphur.

EFFECT: improved method.

1 cl, 4 ex, 1 tbl

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RU 2 387 673 C1

Authors

Balanovskij Nikolaj Vladimirovich

Zorina Ariadna Ivanovna

Il'Inskij Andrej Aleksandrovich

Karpova Alla Viktorovna

Kamentseva Zoja Maksimovna

Ledovskikh Gennadij Ivanovich

Roshchin Aleksandr Vasil'Evich

Balashova Galina Leonidovna

Dates

2010-04-27Published

2008-08-15Filed