FIELD: chemistry.
SUBSTANCE: invention concerns application of chrome source as catalyst activator in combination with precipitated iron catalyst in high-temperature Fischer-Tropsch process for transformation of CO and H2 reagents into reaction products in the form of hydrocarbons and possible hydrocarbon oxygenates by contacting CO and H2 with chrome source combined with precipitated iron catalyst in the course of two-phase high-temperature Fischer-Tropsch reaction. Reaction is performed in reactor with fluidised layer, reactants and reaction products are in gas phase, and catalyst is in solid phase. Chrome source concentration in precipitated iron catalyst comprises 0.3-1 g of chrome per 100 g of iron. Beside chrome source, precipitated iron catalyst includes at least one additional catalyst activator. Also invention claims two-phase high-temperature Fischer-Tropsch process.
EFFECT: enhanced catalyst activity, reduced organic acid formation and methane concentration.
12 cl, 1 tbl
Title | Year | Author | Number |
---|---|---|---|
METHOD OF ACTIVATING FISCHER-TROPSCH SYNTHESIS CATALYST | 2008 |
|
RU2450044C2 |
METHOD OF OBTAINING CATALYST OF HYDROCARBON SYNTHESIS AND ITS APPLICATION IN PROCESS OF HYDROCARBON SYNTHESIS | 2009 |
|
RU2502559C2 |
HYDROCARBON SYNTHESIS METHOD | 2008 |
|
RU2450043C2 |
METHOD FOR HYDROCARBON SYNTHESIS | 2008 |
|
RU2442815C2 |
METHOD OF PRODUCING CATALYST FOR SYNTHESIS OF HYDROCARBONS AND USE THEREOF IN SYNTHESIS OF HYDROCARBONS | 2008 |
|
RU2461422C2 |
Fe-BASED CATALYST FOR FISCHER-TROPSCH SYNTGHESIS, METHOD OF ITS MANUFACTURING AND APPLICATION | 2010 |
|
RU2468863C1 |
FISCHER-TROPSCH SYNTHESIS CATALYST CONTAINING NITRIDE CARRIER, AND METHOD FOR ITS PREPARATION, AND ITS APPLICATION | 2018 |
|
RU2760904C2 |
FISCHER-TROPSCH SYNTHESIS CATALYST, METHOD FOR PREPARATION AND USE THEREOF | 2010 |
|
RU2478006C1 |
PRODUCTION OF AROMATIC COMPOUNDS FROM METHANE | 2007 |
|
RU2462444C2 |
FISCHER-TROPSCH CATALYST PREPARED USING HIGH-PURITY IRON-CONTAINING PRECURSOR (VARIATIONS) | 2002 |
|
RU2299764C2 |
Authors
Dates
2010-06-20—Published
2004-11-18—Filed