FIELD: chemistry.
SUBSTANCE: present invention relates to a continuous method of producing methylmercaptan which is a valuable organic synthesis intermediate product. The proposed method involves obtaining methylmercaptan through contact of a thoroughly mixed mixture of oxides of carbon, sulphur or hydrogen sulphide and hydrogen at high temperature and pressure in the presence of a moulded solid catalyst which contains K2MoO4 as an active component, an active promoter, where the active promoter is a mixture of oxides or a mixture of sulphides or a mixture of sulphides and oxides of metals selected from a group consisting of iron, cobalt, nickel, lanthanum, cerium and manganese and optionally a carrier.
EFFECT: preparation of a new catalyst for obtaining methylmercaptan and a method which uses this catalyst, which increases methylmercaptan output.
37 cl, 6 ex, 5 tbl
Title | Year | Author | Number |
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CATALYST FOR OBTAINING METHYL MERCAPTAN | 2008 |
|
RU2497588C2 |
METHOD FOR CONTINUOUS PRODUCTION OF METHYL MERCAPTAN FROM CARBON- AND HYDROGEN-CONTAINING COMPOUNDS | 2008 |
|
RU2485099C2 |
MOLYBDENUM-CONTAINING CATALYST, METHOD OF ITS PRODUCTION AND METHOD TO PRODUCE METHYL MERCAPTAN | 2007 |
|
RU2436626C2 |
METHOD OF OBTAINING METHYLMERCAPTANE FROM DIALKYL SULPHIDES AND DIALKYL POLYSULPHIDES | 2008 |
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RU2490255C2 |
METHOD OF LOWERING TOTAL SULFUR LEVEL IN GASES INCLUDING HYDROGEN SULFIDE AND OTHER SULFUR-CONTAINING COMPONENTS | 1997 |
|
RU2177361C2 |
CATALYST FOR SYNTHESIS OF METHYLMERCAPTAN AND METHOD OF ITS PRODUCTION | 1997 |
|
RU2190467C2 |
METHOD OF REMOVING SULPHUR COMPOUNDS AND CARBON DIOXIDE FROM GAS STREAM | 2006 |
|
RU2429899C2 |
METHOD OF CLEANING GASES PRODUCED AT GASIFICATION PLANT | 2006 |
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RU2417825C2 |
CATALYST, METHOD OF PREPARING SAID CATALYST AND METHOD OF REMOVING SULPHUR DIOXIDE FROM GAS EMISSIONS | 2008 |
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RU2369436C1 |
METHYLMERCAPTANE SYNTHESIS CATALYST AND METHOD OF PREPARATION THEREOF | 1997 |
|
RU2191069C2 |
Authors
Dates
2010-07-10—Published
2004-09-29—Filed