FIELD: chemistry.
SUBSTANCE: invention relates to a method of producing hydride complexes [(CpMe)2Zr(µH)]2(µH)2(AlR3)2 having general formula (1a-c) , where R=Me(a), Et(b), Bui(c). The method involves reacting substituted bis-methylcyclopentadienyl zirconium dihydride (CpMe)2ZrH2 with organoaluminium compounds (AlMe3, AIEt3, AlBui 3), taken in molar ratio 1:1, in toluene in an argon atmosphere at temperature of approximately 10°C and normal pressure.
EFFECT: invention enables to obtain compounds with higher hydro-aluminising capacity with respect to olefins.
1 cl, 2 ex
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Authors
Dates
2010-07-20—Published
2008-08-19—Filed