FIELD: chemistry.
SUBSTANCE: invention refers to organic synthesis, specifically to technology of new aluminium organic compound 6-ethyl-6-aluminaspiro[3.4]octane. Method is implemented by interaction of methylene cyclobutane and triethyl aluminium with zirconacen bichloride catalyst in argon atmosphere in hexane at room temperature during 8-12 h.
EFFECT: production of compounds which can be applied as catalyst system component in oligomerisation and polymerisation of olefine, diene and acetylene hydrocarbons, as well as in fine organic and organometallic synthesis.
1 cl, 1 ex, 1 tbl
Title | Year | Author | Number |
---|---|---|---|
SPIRO[3,4]OCTAN-6-OL SYNTHESIS METHOD | 2007 |
|
RU2378245C2 |
METHOD OF OBTAINING 1-ETHYL-1,2,3,3a,4,5,6,7,8,9-DECAHYDROCYCLONONE[b]ALUMINACYCLOPENTANE | 2007 |
|
RU2342393C2 |
METHOD OF OBTAINING 1-ETHYL-2,3,4,5,6,7,8,9-OCTAHYDRO-1H-CYCLOOCTA-[b]-ALUMINACYCLOPENTANE | 2007 |
|
RU2342395C2 |
METHOD OF 6-HYDROXYSPIRO[3,4]OCTANE-6-ALKYLCARBOXYLATES OBTAINMENT | 2007 |
|
RU2355677C1 |
METHOD OF OBTAINING 6-THIASPIRO[3,4]OCTANE | 2007 |
|
RU2368606C2 |
METHOD OF SPIRO[3,3]HEPTANE PRODUCTION | 2007 |
|
RU2350595C1 |
METHOD OF SPIRO[3,4]OCT-6-YLFORMIATE OBTAINMENT | 2007 |
|
RU2355676C2 |
METHOD OF OBTAINING 7-CHLORO-1,2,3,4,5,6,7,8,9,10,11,12,13-DODECAHYDRODICYCLO-OCTA-[b,d]-ALUMINACYCLOPENTADIENE | 2007 |
|
RU2342394C2 |
METHOD OF COMBINED PRODUCTION OF TETRACYCLO [5.4.1.0.0]DODEC-3-ENE-9-SPIRO(3'-ETHYL-3'-ALUMINACYCLOPENTANE) AND TETRACYCLO [5.4.1.0.0]DODEC-4-ENE-9-SPIRO(3'-ETHYL-3'-ALUMINACYCLOPENTANE) | 2008 |
|
RU2376311C2 |
METHOD OF PRODUCING TRICYCLO[4,2,1,0]-NONANE-3-SPIRO-1'-BUTANE | 2008 |
|
RU2373174C1 |
Authors
Dates
2008-12-27—Published
2007-01-30—Filed