FIELD: process engineering.
SUBSTANCE: invention can be used for exhaust gas after burning in ICE. Aqueous mix containing zirconium and cesium and one of lanthanides, ether than cerium, and yttrium is obtained. Obtained mix is heated to 100 °C to produce precipitate in the form of suspension in reaction medium which is brought up to the level of alkaline pH. First, added is additive selected from anion surfactants, nonionic surfactants, polyethylene glycols, carbonic acids and their salts, and surfactants of the type of carboxymethylated oxethylates of fat alcohols is added to produced medium and, then precipitate is separated. In compliance with another version, first, precipitate is liberated from reaction medium and, thereafter, aforesaid additive is added to precipitate. Precipitate is calcinated in atmosphere of inert gas or in vacuum at 900 °C and, then in oxidising atmosphere at 600 °C. Produced composition contains cerium oxide in amount of not over 50 wt %. Reduction degree after calcination in atmosphere of air at 600 °C makes at least 95 %, while specific surface after calcination at 1100 °C for 4 h makes at least 15 m2/g.
EFFECT: possibility to produce catalytic systems that feature efficiency in exhaust gas treatment.
18 cl, 2 tbl, 6 ex
Title |
Year |
Author |
Number |
MIXED OXIDE BASED ON CERIUM AND ZIRCONIUM |
2017 |
- Jorge Coelho Marques, Rui Miguel
- Ifrah, Simon
- Chabert, Boris
|
RU2753046C2 |
COMPOSITION BASED ON OXIDES OF ZIRCONIUM, CERIUM, LANTHANUM AND YTTRIUM, GADOLINIUM OR SAMARIUM WITH HIGH SPECIFIC SURFACE AND REDUCING ABILITY, METHOD OF ITS PRODUCTION AND APPLICATION AS CATALYST |
2007 |
- Ljarshe Oliv'E
- Verd'E Stefan
- Roar Ehmmanjuehl'
|
RU2404855C2 |
COMPOSITION BASED ON CERIUM OXIDE AND ZIRCONIUM OXIDE HAVING SPECIFIC POROSITY, METHOD OF PRODUCTION AND USE IN CATALYSIS |
2010 |
|
RU2509725C2 |
MIXED CERIUM AND ZIRCONIUM OXIDES |
2016 |
- Ifrah, Simon
- Li, Wei
- Buissette, Valerie
- Denaire, Stephane
- Marques, Rui
|
RU2707888C1 |
COMPOSITIONS BASED ON ZIRCONIUM OXIDE USED AS TERNARY CATALYSTS |
2016 |
- Harris, Deborah Jayne
- Scapens, David Alastair
|
RU2727187C2 |
COMPOSITION BASED ON ZIRCONIUM, CERIUM AND YTTRIUM OXIDES WITH INCREASED RESILIENCE, METHOD OF OBTAINING AND APPLICATION IN CATALYSIS |
2009 |
- Ljarshe Oliv'E
- Roar Ehmmanjuehl'
- Ifra Simon
|
RU2468855C2 |
COMPOSITION BASE ON OXIDES OF ZIRCONIUM, CERIUM, YTTRIUM, LANTHANUM AND OTHER RARE-EARTH METALS, METHOD OF ITS PRODUCTION AND USE IN CATALYSIS |
2007 |
- Ljarshe Oliv'E
- Verd'E Stefan
- Roar Ehmmanjuehl'
- Khuan Ajmin
|
RU2398629C2 |
COMPOSITION, BASED ON OXIDES OF ZIRCONIUM, CERIUM AND OTHER RARE EARTH METAL WITH LOWER REDUCTABILITY TEMPERATURE, METHOD OF OBTAINING AND APPLICATION IN FIELD OF CATALYSIS |
2011 |
- Ifra Simon
- Roar Ehmmanjuehl'
- Ehrnande Zhjul'En
- Denehr Stefan
|
RU2518969C2 |
PRECIPITATED AND CALCINED COMPOSITION BASED ON ZIRCONIUM OXIDE AND CERIUM OXIDE |
2014 |
- Okhtake Naotaka
- Sasaki Tosikhiro
- Tokuda Dzun
- Roar Emmanyuel
|
RU2648072C2 |
MIXED OXIDE OF CERIUM AND ANOTHER RARE-EARTH ELEMENT WITH HIGH SPECIFIC SURFACE AREA, METHOD OF OBTAINING SAID OXIDE AND USE IN CATALYSIS |
2008 |
- Jokota Kazukhiko
- Okhtake Naotaka
|
RU2445268C2 |