FIELD: chemistry.
SUBSTANCE: invention relates to a method for catalytic carboxylation of alkylene oxides with carbon dioxide in the presence of a catalyst composition and water, where the catalyst composition contains an alkali metal halide and a macro-cyclic chelating compound and where water is present in amount of at least 0.05 mol per mole of alkylene oxide.
EFFECT: high conversion and rate of the process.
10 cl, 3 tbl, 12 ex
| Title | Year | Author | Number |
|---|---|---|---|
| METHOD OF PRODUCING ALKYLENE GLYCOL | 2006 |
|
RU2410370C2 |
| METHOD OF OBTAINING ALKYLENE GLYCOL | 2009 |
|
RU2490247C2 |
| CATALYTIC HYDROLYSIS OF ALKYLENE OXIDES | 1998 |
|
RU2203879C2 |
| METHOD OF PRODUCING ALKYLENE GLYCOL | 2008 |
|
RU2477718C2 |
| METHOD OF PRODUCING ALKYLENE GLYCOL | 2008 |
|
RU2467995C2 |
| METHOD OF PRODUCING ALKYLENE GLYCOL | 2008 |
|
RU2466123C2 |
| METHOD OF OBTAINING ALKYLENECARBONATE AND ALKYLENEGLYCOL | 2009 |
|
RU2506123C2 |
| METHOD AND APPARATUS FOR PRODUCING ALKYLENE GLYCOL | 2015 |
|
RU2699547C2 |
| METHOD OF OBTAINING ALKYLENECARBONATE AND/OR ALKYLENEGLYCOL | 2009 |
|
RU2506124C2 |
| METHOD OF PRODUCING ALKYLENE GLYCOL | 2008 |
|
RU2480446C2 |
