FIELD: physics.
SUBSTANCE: method of analysing optical and structural isomers involves separation of the analysed mixture on a composite liquid crystal sorbent which contains a smectic-nematic liquid crystal of 4-n-octyloxy-4'-cyanobiphenyl and chiral macrocyclic modified β-cyclodextrin. The retention characteristic of the analysed substances is then determined from results of measuring chromatographic signals from obtained chromatographs. The chiral macrocyclic additive used is modified β-cyclodextrin - (heptakis-2,3,6-O-acetyl) - β-cyclodextrin in amount of 10% of the mass of the liquid crystal.
EFFECT: high enantioselectivity of analysis with retention of structural selectivity, which enables to separate optical and structural isomers in a single chromatographic analysis cycle.
1 tbl, 1 ex
| Title | Year | Author | Number |
|---|---|---|---|
| METHOD OF ANALYSIS OF STRUCTURAL AND OPTIC ISOMERS | 2013 |
|
RU2528126C1 |
| METHOD OF ANALYSING OPTICAL AND STRUCTURAL ISOMERS | 2011 |
|
RU2494390C2 |
| METHOD OF GAS CHROMATOGRAPHIC ANALYSIS OF OPTICAL AND STRUCTURAL ISOMERS | 2007 |
|
RU2356047C2 |
| METHOD OF ANALYSING OPTICAL ISOMERS UNDER EFFECT OF ELECTRIC FIELD ON SORBENT AND APPARATUS FOR REALISING SAID METHOD | 2010 |
|
RU2447433C2 |
| SORBENT FOR RESOLUTION OF OPTICAL ISOMERS AND A METHOD FOR PREPARATION THEREOF | 2004 |
|
RU2255802C1 |
| METHOD FOR PREPARATION OF ENANTIOSELECTIVE SORBENT | 2008 |
|
RU2363538C1 |
| SORBENT FOR OPTIC ISOMER CHROMATOGRAPHY AND METHOD OF ITS OBTAINMENT | 2006 |
|
RU2348455C2 |
| SORBENT AND METHOD OF PREPARATION THEREOF | 2001 |
|
RU2203730C1 |
| LIQUID CRYSTAL SPATIAL LIGHT MODULATOR (VERSIONS) | 2007 |
|
RU2340923C1 |
| METHOD OF CHIRAL SORBENTS PRODUCTION | 2007 |
|
RU2339445C1 |
