FIELD: chemistry.
SUBSTANCE: invention relates to use of an antioxidant to increase resistance of a polyolefin composition meant for making pipes to decomposition caused by contact with water, which contains CIO2. The antioxidant is selected from a) a group of phenols of formula I, where R is an unsubstituted or substituted aliphatic or aromatic hydrocarbon radical which can contain heteroatoms, or R is a heteroatom, R' and R" independently denote an unsubstituted or substituted hydrocarbon radical which can contain heteroatoms, or H, X1, X2 and X3 independently denote an unsubstituted or substituted hydrocarbon radical which can contain heteroatoms, or H or OH, where at least X1, X2 or X3 is OH, n assumes values from 1 to 4, and at least one of the phenol substitutes R, R' and/or R" contains at least one sulphur, phosphorus and/or nitrogen heteroatom or from b) amine compounds of formula II, where R1, R2, R3, R4, R5 and R6 independently denote a hydrogen atom or an aliphatic or aromatic hydrocarbon radical, possibly containing heteroatoms, or selected from c) sulphur-containing compounds of formula Ra-S-Rb III, where Ra and Rb independently denote an aliphatic or aromatic hydrocarbon radical, possibly containing heteroatoms.
EFFECT: antioxidant used has low susceptibility to extraction with water carried by a pipe made from such a polyolefin composition.
7 cl, 1 tbl, 2 ex
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Authors
Dates
2011-03-20—Published
2007-09-26—Filed