FIELD: chemistry.
SUBSTANCE: invention relates to production of titanium dioxide used in making photoactive catalysts, organosilicon and Thiokol sealants. Ammonium and titanyl sulphate are preheated to temperature 650-850°C at a rate of 3-10 deg/min in the presence of a zinc compound and then thermally treated at that temperature for 0.2-5.5 hours. The zinc compound used is zinc carbonate or zinc nitrate, taken in amount of 0.05-0.25 wt % in terms of ZnO relative the content of TiO2 in ammonium and titanyl sulphate. The gas phase which contains volatile ammonium and sulphur compounds is trapped with dilute ammonium solution to obtain ammonium sulphate.
EFFECT: invention enables to increase the specific surface area of titanium dioxide powder with anatase structure to 70 m2/g and lowers bulk weight to 350 g/dm3, lowers temperature of the process, increases efficiency of using the starting material.
2 cl, 4 ex
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Authors
Dates
2011-04-10—Published
2009-11-06—Filed