FIELD: chemistry.
SUBSTANCE: invention relates to inorganic chemistry and can be used to produce aluminium fluoride. Aluminium hydroxide is mixed with an excess of up 20% ammonium fluoride or hydrofluoride. The mixture is heated to 126-238°C and then kept at that temperature until complete separation of ammonia gas and water vapour to obtain ammonium cryolite. The ammonium cryolite undergoes thermal decomposition at temperature higher than 350°C until complete separation of ammonia gas and hydrogen fluoride to obtain aluminium fluoride.
EFFECT: invention enables to carry out an anhydrous continuous process in a single chemical apparatus - a tubular revolving furnace with two heating zones.
2 dwg
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Authors
Dates
2011-06-20—Published
2009-12-21—Filed