FIELD: chemistry.
SUBSTANCE: present invention relates to organoaluminium synthesis catalysts, specifically to a catalyst for synthesis of 1-ethyl-2,3-dialkyl(phenyl)aluminacyclopent-2-enes, which can be used as components of catalyst systems in oligo- and polymerisation of olefin, diene and acetylene hydrocarbons, as well as in fine organic and organometallic syntheses. The disclosed catalyst contains a Cp2HfCl2 complex.
EFFECT: Cp2HfCl2 catalyst enables to obtain desired products - 1-ethyl-2,3-dialkyl(phenyl)aluminacyclopent-2-enes without using pyrophoric initial "AOC" with high selectivity.
1 tbl, 1 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD OF OBTAINING 10-ETHYL-11,12-DIALKYL-10-ALUMINABICYCLO [7,3,0]DODECA-8,11-DIENES | 2007 |
|
RU2348640C1 |
METHOD OF COMBINED PREPARATION OF 1-ETHYL -2,3-DIACKYL (PHENYL)ALUMACYCLOPROPENES, 1-ETHYL-2,3-DIALKYL (PHENYL)ALUMACYCLOPENT-2-ENES AND 1-ETHYL-2,3,4,5-TETRAALYLALUMACYCLOPENTADIENES | 1999 |
|
RU2160269C1 |
METHOD FOR COMBINED SYNTHESIS OF 1-ETHYL-2-ALKYLIDENEALUMINACYCLOPENTANES AND 1-ETHYL-2-METHYLENE-3-ALKYLALUMINACYCLOPENTANES | 2009 |
|
RU2423370C2 |
METHOD OF COMBINED SYNTHESIS OF 1-ETHYL-2-METHYLENE-3-ALKYL-ALUMACYCLOPROPANES AND 1-ETHYL-1,1-DI-(ALK-1'-ENE-3'-YL)-ALANS | 2000 |
|
RU2180665C1 |
METHOD OF PRODUCING 1-ETHYL-3-ALKYLALUMINIUM CYCLOPENTANES | 2009 |
|
RU2433132C2 |
METHOD FOR PREPARING 10-CHLORO-1,7,8,9-TETRAALKYL-4-METHYL-4-AZA-10-ALUMINATRICYCLO[5.2.1.0]DEC-8-ENE-3,5-DIONES | 2005 |
|
RU2295529C1 |
METHOD OF OBTAINING 1-CHLORO-3,4-DIALKYL-2,5-BIS[3-(1-ALKINYL)PHENYL]-1H-ALUMINOLS | 2007 |
|
RU2348639C1 |
METHOD OF COMBINED PREPARATION OF 1-(DIALKYLAMINE)-2,3- DIALKYL(PHENYL)ALUMACYCLOPROPENES, 1-(DIALKYLAMINE)-2,3- DIALKYL(PHENYL)ALUMACYCLOPENT-2-ENES AND 1- (DIALKYLAMINE)-2,3,4,5-TETRAALKYLALUMACYCLOPENTADIENES | 1999 |
|
RU2157374C1 |
METHOD FOR PREPARING 1,7,8,9-TETRAALKYL-10-ETHYL-4-OXO-10-ALUMINATRICYCLO[5,2,1,0]-DEC-8-ENE-3,5-DIONES | 2004 |
|
RU2275374C2 |
METHOD FOR PREPARING 2,6-DIETHYL-5,7-DIPHENYL-1,2,3,3a,4,6,8,8a-OCTAHYDROALUMACYCLOPENTADIENO[3,4-f]-ISOALUMAINDOLE | 2004 |
|
RU2280037C2 |
Authors
Dates
2011-07-10—Published
2009-07-02—Filed