FIELD: chemistry.
SUBSTANCE: invention relates to a polymer of formula (I): In-[(A)x-(B)y-( A')x-(E)z]n, obtained via controlled free-radical polymerisation using nitroxyl radicals with excess acrylate. In is a fragment of an initiator. A and A' are identical or different monomers selected from a group comprising methylacrylate, ethylacrylate, ethylhexylacrylate, propylacrylate, cyclohexylacrylate, hydroxyethylacrylate, n-butylacrylate, styrene and vinylpyridine. The amount of unsubstituted C1-C22 alkyl acrylic esters and/or C1-C22 alkyl methacrylic esters is more than 30 wt %. B is propargylacrylate. E is a group containing at least one stable nitroxyl free radical.
EFFECT: obtaining polymers suitable for use as a wetting or dispersing agent for dyes, as well as starting material for all reactions starting with alkyne or for hydrosilylation reactions.
8 cl, 1 tbl, 3 ex
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Authors
Dates
2011-07-27—Published
2006-08-21—Filed